Poulenc, C.
Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570
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Poulenc, C.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78
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Gmelin Handbook: P: MVol.C, 211, page 484 - 487
H2O in water
hydrolysis; formation of H3PO2, H3PO3, H3PO4, phosphines and H2;;
参考文献
Treadwell, W. D.; Beeli, C.
Helvetica Chimica Acta, 1935 , vol. 18, p. 1161 - 1171
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Gmelin Handbook: P: MVol.C, 251, page 573 - 576
ammonia; magnesium oxide in nitric acid
heating a soln. of trimetaphosphimic acid in aq. HNO3 with NH3 soln. and magnesia for 7 min; dissolving the formed mixture of Mg salts, H4P2O7 and H3PO4 in HNO3; addn. of NH3 soln.; formation of an ppt.; addn. of AgNO3 to the filtrate;; pptn. of Ag3P2NO6H2;;
参考文献
Stokes, H. N.
American Chemical Journal, 1896 , vol. 18, p. 629 - 663
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Raab, R.
Diss. Erlangen 1915, S. 23
water in neat (no solvent)
fast decomposition at ambient temperature, mol ratio of products RH2PO4:R2HPO4:H3PO4 = 2:1:1;;
参考文献
Raetz, R.; Thilo, E.
Liebigs Annalen der Chemie, 1951 , vol. 572, p. 173 - 189
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Thilo, E.; Woggon, H.
Z. Anorg. Chem., 1954 , vol. 277, p. 17 - 26
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Gmelin Handbook: P: MVol.C, 128, page 294 - 297
byproducts: H2; 175-420°C, 20-530 atm; reaction is faster at the end;
参考文献
Hackspill, L.
Chimie et Industrie (Paris), 1931 , vol. 25, p. 1058 - 1063
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Ipatiew, W. N.; Freitag, G.
Z. Anorg. Chem., 1933 , vol. 215, p. 388 - 414
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Gmelin Handbook: P: MVol.B, 3.4.1.5, page 276 - 281
