NH4Cl in neat (no solvent) High Pressure; mixt. of ZrV2, NH4Cl milled at room temp. (0.5 h); placed into autoclave; vacuumized to 1 Pa (0.5 h) at room temp.; allowed to stay (0.5 h); NH3pressure - 0.6-0.8 MPa; heated at 450°C for 3 h; cooled to 20.de ree.C; heated at 450°C (33 h); treated twice with abs. EtOH under stirring for 1 h at room temp. or heated in vac. of about 1 Pa for 3 h at 300°C; identified by X-ray diffraction;
参考文献
Fokin; Fokina; Tarasov
Russian Journal of Inorganic Chemistry, 2012 , vol. 57, # 1 p. 21 - 23
Fowles, G. W. A.; Lanigan, P. G.; Nicholls, D.
Chemistry and Industry (London, United Kingdom), 1961 , p. 1167 - 1168
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Gmelin Handbook: V: MVol.B1, 77, page 210 - 213
