反式-2-苯基-2-丁烯合成路线 （共 42 条）
反应条件
Nafion-H; acetic anhydride in dichloromethane
T=20°C; Dehydration; 2 h;
参考文献
Kumareswaran; Pachamuthu; Vankar
Synlett, 2000 , # 11 p. 1652 - 1654
反应条件
3-(diphenylphosphino)propionic acid benzyl ester; lt;(η3-C4H7)Pd(cod)gt;BF4; P,O ligand in dichloromethane
P=22501.8 Torr; 17 h; Ambient temperaturevariuos ligands; Product distribution;
参考文献
Hovestad, Neldes J.; Eggeling, Eva B.; Heidbuechel, H. Joerg; Jastrzebski, Johann T. B. H.; Kragl, Udo; Keim, Wilhelm; Vogt, Dieter; Van Koten, Gerard
Angewandte Chemie - International Edition, 1999 , vol. 38, # 11 p. 1655 - 1658
反应条件
[(R)-1,1'-spirobiindane-7,7'-diyl] diisopropylamidophosphite; Na[B(3,5-(CF3)2C6H3)4]; (η3-allyl)2Pd(cod)BF4 in toluene
T=25°C; P=750.06 Torr; 1 h; Title compound not separated from byproducts;
参考文献
Shi, Wen-Jian; Xie, Jian-Hua; Zhou, Qi-Lin
Tetrahedron Asymmetry, 2005 , vol. 16, # 3 p. 705 - 710
反应条件
1: sec-phenethyl alcohol With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 Angstroem MS in dichloromethane
2: (ethyl)-triphenylphosphonium bromide With n-butyllithium in tetrahydrofuran; hexane; dichloromethane
T=-78 - 20°C; Wittig olefination;
参考文献
MacCoss, Rachel N.; Balskus, Emily P.; Ley, Steven V.
Tetrahedron Letters, 2003 , vol. 44, # 42 p. 7779 - 7781
反应条件
P0 silica
T=40°C; reactions without P0 silica in cyclohexane at the various temperatures; Rate constant;
参考文献
Leffler, J.E.; Barbas, J.T.
Journal of the American Chemical Society, 1981 , vol. 103, # 26 p. 7768 - 7773
反应条件
boron trifluoride diethyl etherate; nickel in dichloromethane
参考文献
Kawata,N. et al.
Bulletin of the Chemical Society of Japan, 1974 , vol. 47, p. 413 - 416
反应条件
P0 silica
T=55°C; other temperatures, photolysis, additional reagents (PhC(CH3)2CH2COOH, coadsorbed O2), possible ways of the products formation; Product distributionRate constantKinetics;
参考文献
Leffler, J.E.; Barbas, J.T.
Journal of the American Chemical Society, 1981 , vol. 103, # 26 p. 7768 - 7773
参考文献
Wilson; Roberts; Young
Journal of the American Chemical Society, 1949 , vol. 71, p. 2019
反应条件
n-butyllithium in diethyl ether; hexane
Heating;
参考文献
Kawai, Yasushi; Inaba, Yoshikazu; Tokitoh, Norihiro
Tetrahedron Asymmetry, 2001 , vol. 12, # 2 p. 309 - 318
反应条件
1: 10 percent / NaTeH / ethanol / 2.5 h / Ambient temperature
2: 1.) butyllithium / 1.) ether/hexane
View Scheme
参考文献
Barton, Derek H. R.; Bohe, Luis; Lusinchi, Xavier
Tetrahedron, 1990 , vol. 46, # 15 p. 5273 - 5284
