叔丁基二甲基(2-丙炔氧基)硅烷合成路线 （共 34 条）
反应条件
1H-imidazole in dichloromethane T=0°C; 1 h;
参考文献
Higashino, Masato; Ikeda, Naoko; Shinada, Tetsuro; Sakaguchi, Kazuhiko; Ohfune, Yasufumi
Tetrahedron Letters, 2011 , vol. 52, # 3 p. 422 - 425
反应条件
1H-imidazole; 4-(N,N-dimethlyamino)pyridine in dichloromethane T=0°C;
参考文献
Maleczka Jr., Robert E.; Ghosh, Banibrata; Gallagher, William P.; Baker, Aaron J.; Muchnij, Jill A.; Szymanski, Amy L.
Tetrahedron, 2013 , vol. 69, # 19 p. 4000 - 4008
反应条件
1H-imidazole in N,N-dimethyl-formamide T=20°C; 22 h;
参考文献
Layton, Mark E.; Morales, Carl A.; Shair, Matthew D.
Journal of the American Chemical Society, 2002 , vol. 124, # 5 p. 773 - 775
反应条件
1: ethyl bromide With magnesium in tetrahydrofuran 2: propargyl alcohol in tetrahydrofuran 0.666667 h; 3: tert-butyldimethylsilyl chloride in tetrahydrofuran 0.833333 h; cooling;
参考文献
Medvedeva; Novokshonov; Mareev; Borisova
Russian Journal of Organic Chemistry, 2003 , vol. 39, # 3 p. 336 - 339
反应条件
1: dimethyl(1,1-dimethylethyl)(2-propynyloxy)silane With n-butyllithium in tetrahydrofuran; hexane T=0 - 20°C; 2.5 h; 2: dibromo-difluoro-methane in tetrahydrofuran; hexane T=-78°C; 2.5 h;
参考文献
You, Zheng-Wei; Jiang, Zhong-Xing; Wang, Bing-Lin; Qing, Feng-Ling
Journal of Organic Chemistry, 2006 , vol. 71, # 19 p. 7261 - 7267
反应条件
1: dimethyl(1,1-dimethylethyl)(2-propynyloxy)silane With n-butyllithium in tetrahydrofuran; hexane T=0 - 20°C; 2: monobromomonochlorodifluoromethane in tetrahydrofuran; hexane T=-80°C;
参考文献
You, Zheng-Wei; Jiang, Zhong-Xing; Wang, Bing-Lin; Qing, Feng-Ling
Journal of Organic Chemistry, 2006 , vol. 71, # 19 p. 7261 - 7267
反应条件
n-butyllithium 1.) THF-hexane, 0 deg C, than 1 h at r.t., 2.) THF-hexane -78 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Kwok, Pui-Yan; Muellner, Frank W.; Chen, Chien-Kuang; Fried, Josef
Journal of the American Chemical Society, 1987 , vol. 109, # 12 p. 3684 - 3692
参考文献
Nicolaou, K. C.; Skokotas, G.; Maligres, P.; Zuccarello, G.; Schweiger, E. J.; et al.
Angewandte Chemie, 1989 , vol. 101, # 9 p. 1255 - 1257
反应条件
ammonium chloride in tetrahydrofuran; water To a stirred soln. of Me3SnCu*Me2S in THF (Ar, -78°C) was added a THF soln. of 3-tert-butyldimethylsiloxypropyne. The mixt. was stirred (6h). Satd. aq. NH4Cl and ether were added; allowed to warm to room temp.; The org. phase was washed (satd. aq. NH4Cl) and dried (MgSO4). Removal of the solvent; flash chromy. (silica gel) provided 3-tert-butyldimethylsiloxy-2-trimethylstannylpropene and (E)-3-tert-butyldimethylsiloxy-1-trimethylstannylpropene.;
参考文献
Canadian Journal of Chemistry, , vol. 66, p. 1425 - 1429
反应条件
water; C46H53F3N4O4P2RuS in acetone T=69 - 72°C; anti-Markovnikov hydration; 36 h;
参考文献
Grotjahn, Douglas B.; Incarvito, Christopher D.; Rheingold, Arnold L.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 20 p. 3884 - 3887
