1-苯基-2-丙烯基-1-酮合成路线 （共 309 条）
反应条件
ethyl-5-(2-hydroxyethyl)-4-methylthiazolium bromide; triethylamine T=90°C; 2 h;
参考文献
Perrier, Helene; Bayly, Christopher; Laliberte, France; Huang, Zheng; Rasori, Roberta; Robichaud, Annette; Girard, Yves; Macdonald, Dwight
Bioorganic and Medicinal Chemistry Letters, 1999 , vol. 9, # 3 p. 323 - 326
反应条件
1: With potassium hydroxide; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in toluene T=20°C; 24 h; Inert atmosphere; 2: With palladium 10 on activated carbon in toluene 4 h; Reflux; regiospecific reaction;
参考文献
Horn, Joachim; Marsden, Stephen P.; Nelson, Adam; House, David; Weingarten, Gordon G.
Organic Letters, 2008 , vol. 10, # 18 p. 4117 - 4120
反应条件
1: With Zhan 1b catalyst in dichloromethane Olefin cross-metathesis; 48 h; Inert atmosphereReflux; 2: With water; Dess-Martin periodane in dichloromethane T=0°C; Dess-Martin oxidation; 3: With ammonium acetate; acetic acid in ethanol T=55°C; 24 h;
参考文献
Donohoe, Timothy J.; Basutto, Jose A.; Bower, John F.; Rathi, Akshat
Organic Letters, 2011 , vol. 13, # 5 p. 1036 - 1039
反应条件
(i) BH3, (ii) H2O, (iii) /BRN= 635987/, THF; Multistep reaction;
参考文献
Neckers,D.C. et al.
Journal of Organic Chemistry, 1971 , vol. 36, p. 1838 - 1840
反应条件
diethyl ether; hydrogen bromide
参考文献
Schoellkopf,U. et al.
Justus Liebigs Annalen der Chemie, 1970 , vol. 737, p. 158 - 169
反应条件
1,4-dibenzyl-[1,2,4]triazolium bromide; 1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane T=25 - 30°C; 2 h; Inert atmosphere; Catalytic behavior; Reagent/catalystConcentrationSolventTemperature;
参考文献
Sun, Zhong-Xin; Cheng, Ying
European Journal of Organic Chemistry, 2012 , # 26 p. 4982 - 4987
反应条件
1: With lithium borohydride in tetrahydrofuran T=20°C; 2: With niobium pentachloride in tetrahydrofuran; 1,4-dioxane T=0 - 20°C; Inert atmosphere;
参考文献
Ravikumar; Yao, Lihua; Fleming, Fraser F.
Journal of Organic Chemistry, 2009 , vol. 74, # 19 p. 7294 - 7299
反应条件
ethanol; sulfuric acid; sodium hydrogencarbonate; hydrazine
参考文献
Bowden; Jones
Journal of the Chemical Society, 1946 , p. 953
参考文献
Nowikow et al.
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 3659; engl. Ausg. S. 3618
反应条件
hydrogenchloride 1.) hexane, overnight, 2.) room temperature, several hours; Multistep reaction;
参考文献
Bays, J. P.; Encinas, M. V.; Small, R. D.; Scaiano, J. C.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 727 - 734
