1: dimethyl(phenyl)silyl chloride With lithium in tetrahydrofuran
T=0°C;
2: With zinc(II) chloride in tetrahydrofuran; diethyl ether
T=0°C;
3: isoprene With copper(l) iodide in tetrahydrofuran; diethyl ether
T=0°C; Further stages. Title compound not separated from byproducts.;
参考文献
Auer, Gertrud; Oestreich, Martin
Chemical Communications, 2006 , # 3 p. 311 - 313
aluminium trichloride in neat (no solvent)
(CH3)2(C6H5)SiCl and (C6H5)2SiCl2 at 180-250°C;;
参考文献
Gmelin Handbook: Si: MVol.C, 44, page 130 - 132
Full Text Show Details
Dow Corning Ltd.
Patent: GB663690 , 1951 ;
C. A., 1952 , p. 11240
Full Text Show Details
Dow Corning Ltd.
Patent: GB663691 , 1951 ;
C. A., 1952 , p. 11229
N,N,N',N',N'',N''-hexamethylphosphoric triamide in toluene
T=20°C; ΔG; Equilibrium constantThermodynamic data;
参考文献
Nilolaev, G. A.; Mileshkevich, V. P.; Vainshtein, P. M.; Shmeleva, O. A.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 9 p. 2098 - 2101,1867 - 1870
