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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-乙炔基苯甲醚
合成路线
（共 378 条）
88-67-5
邻碘苯甲酸
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
71126-50-6
+
29910-92-7
反应条件
copper(l) iodide; caesium carbonate in dimethyl sulfoxide T=25°C; 12 h; Overall yield = 68 percent; Overall yield = 343 mg; regioselective reaction;
参考文献
Kumar, Manian Rajesh; Irudayanathan, Francis Mariaraj; Moon, Joong Ho; Lee, Sunwoo
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3221 - 3230
768-60-5
4-乙炔基苯甲醚
→
反应条件
71993-33-4
反应条件
1: 86 percent / BuLi / tetrahydrofuran / 2 h / 0 °C 2: 95 percent / MnO2 / CH2Cl2 / 25 °C 3: 60 percent / N-chlorosuccinimide / dimethylformamide / 2 h / 100 °C View Scheme
参考文献
Lin, Chi-Fong; Duh, Tsai-Hui; Lu, Wen-Der; Lee, Jeng-Lin; Lee, Chia-Ying; Chen, Chin-Chau; Wu, Ming-Jung
Journal of the Chinese Chemical Society, 2004 , vol. 51, # 1 p. 183 - 186
768-60-5
4-乙炔基苯甲醚
→
反应条件
73744-44-2
2-氟-1-(4-甲氧基苯基)乙酮
反应条件
methanol; Au(Ph3P)+NTf2-; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) T=70°C; 17 h;
参考文献
De Haro, Teresa; Nevado, Cristina
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 16 p. 2767 - 2772
67-56-1
甲醇
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
1046785-13-0
+
73744-44-2
2-氟-1-(4-甲氧基苯基)乙酮
反应条件
1: With Au(Ph3P)+NTf2-; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) T=70°C; 2: With triethylamine
参考文献
De Haro, Teresa; Nevado, Cristina
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 16 p. 2767 - 2772
591-50-4
碘苯
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
3C12H6N2O4(2-)*2Y(3+)*3Pd(2+)*6Cl(1-)*11H2O; 1,8-diazabicyclo[5.4.0]undec-7-ene in water T=90°C; Sonogashira Cross-Coupling; 6 h;
参考文献
Huang, Jinping; Wang, Wei; Li, Hexing
ACS Catalysis, 2013 , vol. 3, # 7 p. 1526 - 1536
55776-34-6
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); potassium carbonate in dimethyl sulfoxide T=150°C; Sonogashira coupling; 1 h; Microwave irradiationInert atmosphere;
参考文献
Kawaguchi, Shin-Ichi; Srivastava, Puneet; Engman, Lars
Tetrahedron Letters, 2011 , vol. 52, # 32 p. 4120 - 4122
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
oxygen; palladium diacetate in tetrahydrofuran T=25°C; Sonogashira coupling; P=760.051 Torr; 1.5 h;
参考文献
Pankajakshan, Sreekumar; Loh, Teck-Peng
Chemistry - An Asian Journal, 2011 , vol. 6, # 9 p. 2291 - 2295
768-60-5
4-乙炔基苯甲醚
+
98-80-6
苯硼酸
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
2,6-dimethylpyridine; oxygen; copper(I) bromide in methanol T=45°C; Sonogashira coupling; P=760.051 Torr; 16 h;
参考文献
Yasukawa, Tomohiro; Miyamura, Hiroyuki; Kobayashi, Sh
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 18 p. 6208 - 6210
768-60-5
4-乙炔基苯甲醚
+
71-43-2
苯
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
1: benzene With iodine; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=20°C; 0.0833333 h; 2: 4-ethynyl-1-methoxy-benzene With piperidine; bis-triphenylphosphine-palladium(II) chloride in 1,2-dichloro-ethane T=70°C; 3 h;
参考文献
Wan, Shun; Wang, Sunewang R.; Lu, Wenjun
Journal of Organic Chemistry, 2006 , vol. 71, # 11 p. 4349 - 4352
462-06-6
氟苯
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
7380-78-1
1-甲氧基-4-苯基乙炔苯
反应条件
n-butyl-magnesium chloride; sodium methylate; sodium; Ca(OH)2 in tetrahydrofuran T=0 - 20°C; Sonogashira Cross-Coupling; 0.0916667 h; Inert atmosphere;
参考文献
Jin, Guanyi; Zhang, Xuxue; Cao, Song
Organic Letters, 2013 , vol. 15, # 12 p. 3114 - 3117
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