n-butyllithium in hexane 1-bromoadamantane (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 15 min, quenched with water; analyzed by GC;
参考文献
Reimann, Werner; Kuivila, Henry G.; Farah, Dan; Apoussidis, Theodorus
Organometallics, 1987 , vol. 6, p. 557 - 565
magnesium; ethylene dibromide in diethyl ether T=35°C; 10 h; no mechanical stirring; Further byproducts given. Title compound not separated from byproducts;
参考文献
Molle, G.; Bauer, P.; Dubois, J. E.
Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4120 - 4128
in diethyl ether; cyclohexane to 1-bromoadamantane (1 mmol) and TMTH (1 mmol) in Et2O at 0°C added LDA (1 mmol, in cyclohexane) under Ar, stirred for 20 min, quenched; analyzed by GLPC;
参考文献
Reimann, Werner; Kuivila, Henry G.; Farah, Dan; Apoussidis, Theodorus
Organometallics, 1987 , vol. 6, p. 557 - 565
