in tetrahydrofuran Under N2, Na{Me2Ga(pz)(OCH2pz)} in THF is added to a soln. of Ni(NO)I in THF, the mixt. is stirred for 3 h at room temp..; Evapn. yields a dark blue oily residue, extn. with benzene, the solid recovered from the filtrate is recrystd. from CH2Cl2/hexane.;
参考文献
Canadian Journal of Chemistry, , vol. 66, p. 101 - 108
→
反应条件
in neat (no solvent) byproducts: H2O; at 270-420°C; monitored by IR, X-Ray diffraction;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 47, # 7 p. 945 - 947
in neat (no solvent) Kinetics; reaction in a diffusion flame above 247°C, H2 as a carrier gas; mechanism discussed;; condensation of the products at -196°C;;
参考文献
Canadian Journal of Chemistry, , vol. 30, p. 473 - 481
in melt under Ar in a tantalum ampoule, in Na melt, heating to 650 °C for7 d, oxygen as the contamination of SmI2; cooling in air to room temp., selected under a microscope;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 632, # 15 p. 2385 - 2388
→
反应条件
in water oxidn. with iodine;
参考文献
Zeitschrift fuer Analytische Chemie, , vol. 32, p. 471
