2,6,N,N-四甲基苯胺合成路线 （共 16 条）
反应条件
titanium tetrachloride in dichloromethane T=0 - 25°C; N-dealkylation; 8 h;
参考文献
Periasamy, Mariappan; Jayakumar, K. Natarajan; Bharathi, Pandi
Journal of Organic Chemistry, 2000 , vol. 65, # 11 p. 3548 - 3550
反应条件
1: With N,N-dimethylthiocarbamoyl chloride in dichloromethane
T=20°C; 2 h;
2: in acetonitrile
3 h; Reflux;
参考文献
Caliskan, Hafize; Zaim, Oemer
Synthetic Communications, 2010 , vol. 40, # 20 p. 3078 - 3083
参考文献
Borkowski; Wagner
Journal of Organic Chemistry, 1952 , vol. 17, p. 1128,1132
反应条件
methanesulfonic acid; hydrogen; [Ru(acac)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane in tetrahydrofuran
T=140°C; 36 h; AutoclaveInert atmosphere;
参考文献
Li, Yuehui; Sorribes, Ivan; Yan, Tao; Junge, Kathrin; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 46 p. 12156 - 12160
Angew. Chem., 2013 , vol. 125, # 46 p. 12378 - 12382,5
反应条件
sodium hydroxide
T=130°C;
参考文献
Friedlaender; Brand
Monatshefte fuer Chemie, 1898 , vol. 19, p. 644
反应条件
lithium aluminium tetrahydride in diethyl ether
Heating;
参考文献
Giumanini, Angelo G.; Verardo, Giancarlo; Polana, Marco
Journal fuer Praktische Chemie (Leipzig), 1988 , vol. 330, # 2 p. 161 - 174
反应条件
(ethyl)-triphenylphosphonium iodide
T=170°C; 0.5 h; Further byproducts given;
参考文献
Selva, Maurizio; Perosa, Alvise; Tundo, Pietro; Brunelli, Davide
Journal of Organic Chemistry, 2006 , vol. 71, # 15 p. 5770 - 5773
反应条件
NaY zeolite
T=150°C; 5 h;
参考文献
Selva, Maurizio; Bomben, Andrea; Tundo, Pietro
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 7 p. 1041 - 1045
参考文献
Borkowski; Wagner
Journal of Organic Chemistry, 1952 , vol. 17, p. 1128,1132
参考文献
Fischer,E.; Windaus
Chemische Berichte, 1900 , vol. 33, p. 347
Show Details
Hofmann,A. W.
Chemische Berichte, 1872 , vol. 5, p. 707
Chemische Berichte, 1877 , vol. 10, p. 1585 Anm. 1
