2,4,6-三甲基苯乙烯合成路线 （共 42 条）
反应条件
oxygen; palladium diacetate; trifluoroacetic acid in water; dimethyl sulfoxide T=70°C; Wacker Oxidation; P=760.051 Torr; 10 h; Sealed tube; regioselective reaction;
参考文献
Wang, Yu-Fei; Gao, Ya-Ru; Mao, Shuai; Zhang, Yan-Lei; Guo, Dong-Dong; Yan, Zhao-Lei; Guo, Shi-Huan; Wang, Yong-Qiang
Organic Letters, 2014 , vol. 16, # 6 p. 1610 - 1613
反应条件
[bis(acetoxy)iodo]benzene; ammonium hydrogen carbonate in methanol; water T=36°C; 12 h; Sealed tube;
参考文献
Xu, Jin-Hui; Jiang, Qing; Guo, Can-Cheng
Journal of Organic Chemistry, 2013 , vol. 78, # 23 p. 11881 - 11886
反应条件
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene
T=20°C; Addition; Hydroboration; 2 h;
2: With sodium hydroxide; water; dihydrogen peroxide in toluene
T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
反应条件
sodium hydroxide; bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; dihydrogen peroxide; 1,4-di(diphenylphosphino)-butane; benzo[1,3,2]dioxaborole
1.) THF, 25 deg C, 16 h, 2.) THF, RT, 3 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Hayashi; Matsumoto; Ito
Tetrahedron Asymmetry, 1991 , vol. 2, # 7 p. 601 - 612
反应条件
1: NOCl / CH2Cl2
2: Et3N / diethyl ether
3: LiAlH4 / diethyl ether
View Scheme
参考文献
Pritzkow,W. et al.
Journal fuer Praktische Chemie (Leipzig), 1965 , vol. 29, p. 123 - 141
反应条件
iodosylbenzene; Mn(III)conjugate in isopropyl alcohol
Yield given;
参考文献
Geier III, G. Richard; Sasaki, Tomikazu
Tetrahedron, 1999 , vol. 55, # 7 p. 1859 - 1870
反应条件
iodosylbenzene; Mn(III)conjugate in chloroform-d1
Yield givenYields of byproduct given;
参考文献
Geier III, G. Richard; Sasaki, Tomikazu
Tetrahedron, 1999 , vol. 55, # 7 p. 1859 - 1870
反应条件
tert.-butylhydroperoxide; ammonia in water
T=105°C; 16 h;
参考文献
Sharif, Muhammad; Gong, Jin-Long; Langer, Peter; Beller, Matthias; Wu, Xiao-Feng
Chemical Communications, 2014 , vol. 50, # 36 p. 4747 - 4750
反应条件
anti-[Cp*Fe-(2,6-diethyl-4,8-dimethyl-s-indaceneiide)-Rh(COD)] in toluene
T=80°C; 7 h; Inert atmosphere; Reagent/catalystTime;
参考文献
Adams; Riviere; Riviere-Baudet; Morales-Verdejo; Dahrouch; Morales; Castel; Delpech; Manriquez; Chavez
Journal of Organometallic Chemistry, 2014 , vol. 749, p. 266 - 274
反应条件
hydrogen in ethanol
T=20°C; P=760.051 Torr; 2 h;
参考文献
Kim, Eunsuk; Jeong, Han Saem; Kim, B. Moon
Catalysis Communications, 2014 , vol. 45, p. 25 - 29
