1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine; tetrabutylammomium bromide in N,N-dimethyl acetamide; water
T=20°C; Heck reaction; 0.25 h;
2: bromobenzene With palladium diacetate in N,N-dimethyl acetamide; water
T=120°C; Heck reaction; 6 h; Further stages. Title compound not separated from byproducts.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
Trimitsis, G. B.; Hinkley, J. M.; TenBrink, R.; Faburada, A. L.; Anderson, R.; et al.
Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 2957 - 2962
1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine; tetrabutylammomium bromide in N,N-dimethyl acetamide; water
T=20°C; Heck reaction; 0.25 h;
2: bromobenzene With 4'-hydroxyacetophenone oxime palladacycle catalyst in N,N-dimethyl acetamide; water
T=120°C; Heck reaction; 6 h; Further stages.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine in water
T=20°C; Heck reaction; 0.25 h;
2: iodobenzene With Kaiser oxime-derived complex on resin base in water
T=120°C; Heck reaction; 6 h; Further stages.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
N-heterocyclic carbene-palladacycle; sodium t-butanolate in tetrahydrofuran
T=70°C; 2 h; Title compound not separated from byproducts;
参考文献
Navarro, Oscar; Marion, Nicolas; Oonishi, Yoshihiro; Kelly III, Roy A.; Nolan, Steven P.
Journal of Organic Chemistry, 2006 , vol. 71, # 2 p. 685 - 692
