2-甲基-1-苯基-丙-2-烯-1-酮合成路线 （共 105 条）
反应条件
2H6-dimethyl sulfide; ozone 1) CDCl3, Cl2CHCHCl2, -50 deg C, 2) r.t., 20 min; Product distribution;
参考文献
Griesbaum, Karl; Zwick, Gerhard
Chemische Berichte, 1986 , vol. 119, # 1 p. 229 - 243
反应条件
1.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0 °C / Inert atmosphere 2.1: Fc-PIP; N-ethyl-N,N-diisopropylamine / toluene / 0.08 h / 0 °C 2.2: 0 °C View Scheme
参考文献
Hu, Bin; Meng, Meng; Jiang, Shanshan; Deng, Weiping
Chinese Journal of Chemistry, 2012 , vol. 30, # 6 p. 1289 - 1294
反应条件
ozone in chloroform-d1 27 h; Ambient temperature; Product distribution;
参考文献
Chemische Berichte, , vol. 119, # 1 p. 229 - 243
反应条件
Iron (III) nitrate nonahydrate; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; oxygen; sodium chloride in 1,2-dichloro-ethane
T=20°C; 6 h;
参考文献
Liu, Jinxian; Ma, Shengming
Organic Letters, 2013 , vol. 15, # 20 p. 5150 - 5153
反应条件
trifluoroacetic acid; iPr2NH2(1+)*CF3COO(1-) in tetrahydrofuran
RefluxPortion-wise addition of paraformaldehyde;
参考文献
Bugarin, Alejandro; Jones, Kyle D.; Connell, Brian T.
Chemical Communications, 2010 , vol. 46, # 10 p. 1715 - 1717
反应条件
tetrakis(triphenylphosphine) palladium(0); carbon monoxide; 2,6-di-tert-butyl-4-methyl-phenol in toluene
T=100°C; P=760 Torr; 3 h;
参考文献
Renaldo, A. F.; Ito, Hiroshi
Synthetic Communications, 1987 , vol. 17, # 15 p. 1823 - 1830
反应条件
tris(4-methoxyphenyl)-phosphine; palladium diacetate in tetrahydrofuran; water
T=60°C; 16 h;
参考文献
Goossen, Lukas J.; Ghosh, Keya
European Journal of Organic Chemistry, 2002 , # 19 p. 3254 - 3267
反应条件
AlCl3, aluminium chloride in carbon disulfide
T=0°C; 2 h;
参考文献
Japan Science and Technology Agency
Patent: US2012/277423 A1, 2012 ;
Location in patent: Page/Page column 26 ;
US 20120277423 A1
反应条件
cerium(III) chloride; sodium iodide in acetonitrile
Dehydration; 9 h; Heating;
参考文献
Bartoli, Giuseppe; Bellucci, Maria C.; Petrini, Marino; Marcantoni, Enrico; Sambri, Letizia; Torregiani, Elisabetta
Organic Letters, 2000 , vol. 2, # 13 p. 1791 - 1793
反应条件
potassium phosphate; bis-triphenylphosphine-palladium(II) chloride in toluene
T=80°C; 4 h;
参考文献
Urawa, Yoshio; Nishiura, Katsutoshi; Souda, Shigeru; Ogura, Katsuyuki
Synthesis, 2003 , # 18 p. 2882 - 2885
