2-甲基-1-苯基-丙-2-烯-1-酮合成路线 （共 105 条）
反应条件
sodium hydroxide in ethanol
15 h; Ambient temperature;
参考文献
Curzu, Maria Michela; Pinna, Gerard Aime; Barlocco, Daniela; Bugatti, Carlo; Cignarella, Giorgio
Synthesis, 1984 , # 4 p. 339 - 342
反应条件
1: 74 percent / SnCl2 / CH2Cl2 / 0 °C
2: DBU / CH2Cl2 / 2 h / Ambient temperature
View Scheme
参考文献
Hayashi, Masaji; Mukaiyama, Teruaki
Chemistry Letters, 1987 , p. 1283 - 1286
反应条件
1: O3 / CD2Cl2 / -91 °C
2: CD2Cl2 / 0.28 h / -50 °C
3: 57 percent Spectr. / CD2Cl2 / 0.08 h / -50 - 25 °C
View Scheme
参考文献
Reich, Hans J.; Hoeger, Carl A.; Willis, W. W., Jr.
Tetrahedron, 1985 , vol. 41, # 21 p. 4771 - 4780
反应条件
1: CD2Cl2 / 0.28 h / -50 °C
2: 57 percent Spectr. / CD2Cl2 / 0.08 h / -50 - 25 °C
View Scheme
参考文献
Reich, Hans J.; Hoeger, Carl A.; Willis, W. W., Jr.
Tetrahedron, 1985 , vol. 41, # 21 p. 4771 - 4780
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; Xtalfluor-E® in dichloromethane
T=20°C; 24 h; Inert atmosphere;
参考文献
Lheureux, Alexandre; Beaulieu, Francis; Bennett, Christopher; Bill, David R.; Clayton, Simon; Laflamme, Franois; Mirmehrabi, Mahmoud; Tadayon, Sam; Tovell, David; Couturier, Michel
Journal of Organic Chemistry, 2010 , vol. 75, # 10 p. 3401 - 3411
反应条件
18-crown-6 ether; potassium carbonate in benzene
T=80°C; 6 h; Reflux;
参考文献
Riofski, Mark V.; John, Jinu P.; Zheng, Mary M.; Kirshner, Julia; Colby, David A.
Journal of Organic Chemistry, 2011 , vol. 76, # 10 p. 3676 - 3683
反应条件
acetic anhydride in acetic acid
T=100°C; ΔH<*>, ΔS<*>; Rate constantThermodynamic dataKinetics;
参考文献
Creary,X.; Geiger,C.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 4151
反应条件
trifluoroacetic anhydride in trifluoroacetic acid
T=25°C; Rate constant;
参考文献
Creary,X.; Geiger,C.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 4151
反应条件
1: 1618 percent / CD2Cl2 / 6 h / Ambient temperature
2: 100 percent / SO2Cl2 / CCl4 / 0.08 h
4: O3 / -78 °C
5: CDCl3 / -30 °C
View Scheme
参考文献
Reich, Hans J.; Hoeger, Carl A.; Willis, W. W., Jr.
Tetrahedron, 1985 , vol. 41, # 21 p. 4771 - 4780
反应条件
triethylamine tris(hydrogen fluoride) in acetonitrile
anodic oxidation;
参考文献
Laurent, Eliane; Tardivel, Robert; Thiebault, Hugues
Tetrahedron Letters, 1983 , vol. 24, # 9 p. 903 - 906
