hydrogen; silica gel; palladium in hexane T=149.9°C; P=7500.6 Torr; variation of pressure and catalyst; Product distribution;
参考文献
Sokol'skii, D. V.; Ualikhanova, A.; Temirbulatova, A. E.; Dembitskii, A. A.; Mailyubaev, B. T.
J. Appl. Chem. USSR (Engl. Transl.), 1988 , vol. 61, # 10 p. 2360 - 2363,2167 - 2170
hydrogen; ruthenium in hexane T=24.9°C; P=760 Torr; also with D2; other catalysts, kinetic isotope effect; Product distribution;
参考文献
Ualikhanova, A.; Temirbulatova, A. E.; Dembitskii, A. A.; Mailyubaev, B. T.; Korolev, A. V.
Russian Journal of Physical Chemistry, 1992 , vol. 66, # 2 p. 240 - 242
Zhurnal Fizicheskoi Khimii, 1992 , vol. 66, p. 460 - 464
in chloroform-d1 slight excess of the diolefine was added to a CDCl3 coln. of Pt-complex, reaction was followed by (1)H NMR until equil. was reached; products were identified by their (1)H NMR spectra;
参考文献
Rakowsky, Margaret H.; Woolcock, John C.; Wright, Laura L.; Green, David B.; Rettig, Michael F.; Wing, Richard M.
Organometallics, 1987 , vol. 6, p. 1211 - 1218
