3-甲基-1-戊炔-3-醇合成路线 （共 98 条）
反应条件
hydrogen; pentacyanocobaltate(II)(3-) in water
T=45°C; P=760 Torr; 10 h; <EtC(Me)(OH)CCH>/<Co> : 1; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
反应条件
1: aq. HCl, CaCl2, CuCl / Cu
2: Zn-Cu
3: H2 / Pd-BaSO4
View Scheme
参考文献
Crombie,L. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1081 - 1090
反应条件
pentacyanocobaltate(II)(3-); hydrogen in water
P=760 Torr; 10 h; different reagent ratio; Product distributionMechanism;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
反应条件
1: palladium/barium sulfate; hexane / Hydrogenation
View Scheme
参考文献
Young; Webb
Journal of the American Chemical Society, 1951 , vol. 73, p. 780
参考文献
Gardner,J.N.
Canadian Journal of Chemistry, 1973 , vol. 51, p. 1416 - 1418
反应条件
diethyl ether; ethylmagnesium bromide
dann mit Pentan-2-on;
参考文献
Nogaideli
Sb. Statei Obshch. Khim., 1953 , p. 1636
Chem.Abstr., 1955 , p. 5283
反应条件
tetraethylammonium bromide; triethylamine; copper(I) bromide
T=140°C; Condensation; dehydration; P=76000 - 114000 Torr; 20 h;
参考文献
Chernysheva; Bogolyubov; Semenov
Chemistry of Heterocyclic Compounds, 1999 , vol. 35, # 2 p. 216 - 224
反应条件
hydrogen; pentacyanocobaltate(II)(3-) in water
T=45°C; P=760 Torr; 10 h; <EtC(Me)(OH)CCH>/<Co> : 1; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
反应条件
1: aq. HCl, CaCl2, CuCl / Cu
2: Zn-Cu
3: H2 / Pd-BaSO4
View Scheme
参考文献
Crombie,L. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1081 - 1090
反应条件
pentacyanocobaltate(II)(3-); hydrogen in water
P=760 Torr; 10 h; different reagent ratio; Product distributionMechanism;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
