K-polysulfide
SO2 is introduced into a soln. of K-polysulfide, satd. by S, at ambient temp.; excess of SO2 reacts with thiosulfate to form trithionate;;
Cohen,S.C. et al.
Journal of Organometallic Chemistry, 1968 , vol. 11, p. 563 - 566
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Gmelin Handbook: F: PerFHalOrg.1, 1.1.6.6, page 195 - 217
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反应条件
in solid
heating stoich. mixt. of Y-, Ba- and Cu-compd. with sulphur in evac. sealed silica tube according to: R. Cloots et al., Solid State Commun. 79 (1991) 615; temp. rise (15 K/h) to 550°C, holding 48 h, silica tube free cooling to room temp.; X-ray diffraction, scanning electron microscopy, energy dispersive X-ray anal.;
参考文献
Cloots, R.; Krekels, T.; Warin, R.; Vandewalle, N.; Ausloos, M.
Journal of Solid State Chemistry, 1995 , vol. 117, p. 151 - 156
