反应条件
KOH; H2SO4 in tetrahydrofuran
condensing MeOH onto mixt. of W-complex and 1-0.75 equiv. of TiCl3 (-196°C), warming to 20°C, addn. of excess H2SO4, stirring for 20 h (in vac. or under N2 or H2), addn. of excess 40percent KOH; distn. into dild. H2SO4; colorimetry of NH3, N2H4; volumetry of free andtotal N2 (after reaction with NaOBr);
参考文献
Chatt, Joseph; Pearman, Alan J.; Richards, Raymond L.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1852 - 1860
