2,3,4,5,6-五氟苯胺合成路线 （共 126 条）
反应条件
tert-butylhypochlorite in tetrachloromethane
T=-30°C;
参考文献
Andreevskaya, O. I.; Markovskii, L. N.; Poleshchuk, O. Kh.; Furin, G. G.; Shermolovich, Yu. G.; Yakobson, G. G.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 4 p. 717 - 722
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 4 p. 817 - 822
反应条件
1: 21 percent / AlBr3 / 2 h / 130 - 140 °C
2: 29 percent / Mg / tetrahydrofuran / 0.17 h / -30 deg C to -10 deg C
View Scheme
参考文献
Traylor, Teddy G.; Magde, Douglas; Luo, Jikun; Walda, Kevin N.; Bandyopadhyay, Debkumar; Wu, Guo-Zhang; Sharma, Vijay S.
Journal of the American Chemical Society, 1992 , vol. 114, # 23 p. 9011 - 9017
反应条件
1: in benzene
T=30°C; 1 h;
2: With 1,1,1,3,3,3-hexamethyl-disilazane; zinc dibromide in benzene
4 h; Heating / reflux;
参考文献
Facchetti, Antonio; Marks, Tobin J.; Wang, Zhiming M.
Patent: US2008/185555 A1, 2008 ;
Location in patent: Page/Page column 12 ;
反应条件
aluminium trichloride
T=70 - 80°C; 12 h; other catalysts, reagents; Product distribution;
参考文献
Savchenko, T. I.; Kolesnikova, I. V.; Petrova, T. D.; Platonov, V. E.
Journal of Fluorine Chemistry, 1983 , vol. 22, p. 439 - 458
反应条件
triethylamine in toluene
4 h; Inert atmosphereReflux;
参考文献
Jiang, Chunfang; Stephan, Douglas W.
Dalton Transactions, 2013 , vol. 42, # 3 p. 630 - 637
反应条件
in tetrachloromethane
T=20°C; 2 h;
参考文献
Zibarev, A. V.; Dolenko, G. N.; Krupoder, S. A.; Mazalov, L. N.; Poleshchuk, O. Kh.; et al.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 347 - 354
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 2 p. 390 - 398
