2,3,4,5,6-五氟苯胺合成路线 （共 126 条）
反应条件
in dimethyl sulfoxide T=25°C; Equilibrium constant;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 25, # 11.1 p. 2041 - 2044
Zhurnal Organicheskoi Khimii, , vol. 25, # 11 p. 2261 - 2265
反应条件
copper(I) bromide; sulfuric acid; copper(II) sulfate; potassium bromide; sodium nitrite; B(3,5-bis(trifluoromethyl)phenyl)4- 1) 0 deg C, dichloromethane, water 2) dichloromethane, water, 100 min, rt.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Iwamoto, Hidetoshi; Sonoda, Takaaki; Kobayashi, Hiroshi
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 535 - 537
参考文献
Gmelin Handbook: F: PerFHalOrg.7, 1, page 1 - 84
反应条件
n-Pentyl nitrite T=80°C; 0.5 h; reaction with different substituted benzenes to different products; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 64, # 3 p. 201 - 216
反应条件
in further solvent(s) solvent: Genetron 113, excess of WF6, at -80°C, allowed to warm slowly to room temp., gently warmed for 15 min to about 30°C, left to stand at room temp. for 2 h; solvent and excess WF6 distilled, warmed to 45°C under dynamic vacuum, recrystn. (trifluoroacetic acid);
参考文献
Fawcett, J.; Griffith, G. A.; Peacock, R. D.; Russell, D. R.
Polyhedron, 1988 , vol. 7, p. 2015 - 2022
反应条件
1: aq. H2O2, (CF3CO)2O / CH2Cl2 / Heating 2: NH3 / diethyl ether / Ambient temperature 3: H2 / Raney-Ni / ethanol View Scheme
参考文献
Gmelin Handbook: F: PerFHalOrg.7, 1, page 1 - 84
反应条件
Cu2Cl2; sulfuric acid; copper(II) sulfate; sodium nitrite; benzene; B(3,5-bis(trifluoromethyl)phenyl)4- 1) 0 deg C, dichloromethane, water, 2) dichloromethane, water , 100 min, rt.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Iwamoto, Hidetoshi; Sonoda, Takaaki; Kobayashi, Hiroshi
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 535 - 537
反应条件
Cu2Cl2; sulfuric acid; copper(II) sulfate; sodium nitrite; B(3,5-bis(trifluoromethyl)phenyl)4- 1) 0 deg C, dichloromethane, water, 5 min 2) dichloromethane, water 100 min, rt.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Iwamoto, Hidetoshi; Sonoda, Takaaki; Kobayashi, Hiroshi
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 535 - 537
反应条件
n-Pentyl nitrite T=80°C; 0.5 h; reaction with different substituted benzenes to different products; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 64, # 3 p. 201 - 216
反应条件
water; fluorine in acetonitrile T=20°C; 5 h; Inert atmosphereFlow reactor;
参考文献
ChemSusChem, , vol. 5, # 2 p. 312 - 319
