2,3,4,5,6-五氟苯胺合成路线 （共 126 条）
反应条件
in not given byproducts: C6F6, C6F5H, C6F5CF3, perfluoroxylolene; Pyrolysis at 580°C, flowrate 15 l/h, 1 h.;
参考文献
Gmelin Handbook: F: PerFHalOrg.7, 1, page 1 - 84
反应条件
ammonium hydroxide T=120°C; 48 h;
参考文献
Selivanova; Pokrovskii; Shteingarts
Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 404 - 409
反应条件
1: N2H4*H2O / dioxane / Heating 2: HI View Scheme
参考文献
Holland,D.G. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 1562 - 1565
反应条件
ammonium hydroxide T=120°C; 48 h;
参考文献
Selivanova; Pokrovskii; Shteingarts
Russian Journal of Organic Chemistry, 2001 , vol. 37, # 3 p. 404 - 409
反应条件
1: aq. H2O2, (CF3CO)2O / CH2Cl2 / Heating 2: NH3 / diethyl ether / Ambient temperature 3: H2 / Raney-Ni / ethanol View Scheme
参考文献
Brooke,G.M. et al.
Journal of the Chemical Society, 1961 , p. 802 - 807
反应条件
1: |Reflux 2: zinc; [NiCl2(py)4] / N,N-dimethyl acetamide; water / 6 h / 70 °C / |Inert atmosphere View Scheme
参考文献
Prikhodko; Adonin; Parmon
Russian Chemical Bulletin, 2009 , vol. 58, # 11 p. 2304 - 2310
Izv. Akad. Nauk, Ser. Khim., 2009 , # 11 p. 2234 - 2239,6
反应条件
1: |Reflux 2: Ru(bpy)3Cl2; zinc / 1-methyl-pyrrolidin-2-one; water / 6 h / 70 °C / |Inert atmosphere View Scheme
参考文献
Prikhodko; Adonin; Parmon
Russian Chemical Bulletin, 2009 , vol. 58, # 11 p. 2304 - 2310
Izv. Akad. Nauk, Ser. Khim., 2009 , # 11 p. 2234 - 2239,6
反应条件
1: p-toluenesulfonyl chloride With pyridine; 4-(N,N-dimethlyamino)pyridine T=20°C; 0.25 h; 2: 2,3,4,5,6-pentafluoroaniline Heating;
参考文献
Dai, Hui-Xiong; Stepan, Antonia F.; Plummer, Mark S.; Zhang, Yang-Hui; Yu, Jin-Quan
Journal of the American Chemical Society, 2011 , vol. 133, # 18 p. 7222 - 7228
反应条件
aluminum tri-bromide T=130 - 140°C; 2 h;
参考文献
Chemische Berichte, , vol. 121, p. 1445 - 1448
反应条件
in dimethyl sulfoxide
T=25°C; Equilibrium constant;
参考文献
Os'kina, I. A.; Vlasov, V. M.; Terekhova, M. I.; Petrov, E. S.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 11.1 p. 2041 - 2044
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 11 p. 2261 - 2265
