(5-氯-1-戊炔基)三甲基硅烷合成路线 （共 13 条）
反应条件
1: NaI / acetone / 24 h / Heating
View Scheme
参考文献
Koft, Emil R.; Smith, Amos B.
Journal of Organic Chemistry, 1984 , vol. 49, p. 832 - 836
反应条件
1.) Li, ether, 2-4 deg C, 30 min 2.) 0 deg C, 30 min; Yield given. Multistep reaction;
参考文献
Koft, Emil R.; Smith, Amos B.
Journal of Organic Chemistry, 1984 , vol. 49, p. 832 - 836
反应条件
1: 5-chloro-1-(trimethylsilyl)-1-pentyne With ethidium Bromide; magnesium in diethyl ether
3 h; Heating;
2: allyl bromide With dilithium tetrachlorocuprate in tetrahydrofuran; diethyl ether
T=-78 - 20°C; Further stages.;
参考文献
Kel'in; Sromek; Gevorgyan
Journal of the American Chemical Society, 2001 , vol. 123, # 9 p. 2074 - 2075
