4-三甲基硅乙炔基苯甲醛合成路线 （共 21 条）
反应条件
copper(l) iodide; diisopropylamine; polymer-supp. 11-(2-[Pd(OAc)2]-1-Mes-3-imidazolyl)undecanol in tetrahydrofuran T=20°C; Sonogashira coupling; 2 h;
参考文献
Sommer, William J.; Weck, Marcus
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 15 p. 2101 - 2113
反应条件
copper(l) iodide; triethylamine in N,N-dimethyl-formamide T=50°C; Sonogashira coupling; 6 h;
参考文献
Worm-Leonhard, Kasper; Meldal, Morten
European Journal of Organic Chemistry, 2008 , # 31 p. 5244 - 5253
反应条件
triphenylphosphine in triethylamine
参考文献
Vicente, Maria da Graca Henriques; Marzilli, Luigi G.
Patent: US2004/116385 A1, 2004 ;
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=25°C; Yields of byproduct given;
参考文献
Thorand; Krause
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8551 - 8553
反应条件
1: 70 percent / n-BuLi 2: 73 percent / Et3N; Pd(PPh3(2Cl2; CuI / tetrahydrofuran View Scheme
参考文献
Tetrahedron Letters, , vol. 48, # 33 p. 5817 - 5820
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=20°C; Sonogashira Cross-Coupling; Inert atmosphereSealed tube;
参考文献
Organic Letters, , vol. 15, # 4 p. 840 - 843
反应条件
in tetrahydrofuran T=20°C; 4 h;
参考文献
Kasahara, Akira; Izumi, Taeko; Shimizu, Iwao; Satou, Masahiro; Katou, Takao
Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 8 p. 2434 - 2440
反应条件
1: in methanol T=20°C; 16 h; 2: With sodium tetrahydroborate in methanol Product distribution / selectivity;
参考文献
Deng, Xiaoliu; Liang, Jimmy T.; Peterson, Matthew; Rynberg, Raymond; Cheung, Eugene; Mani, Neelakandha S.
Journal of Organic Chemistry, 2010 , vol. 75, # 6 p. 1940 - 1947
反应条件
1: potassium carbonate; methanol / 24 h / 20 °C 2: tetrakis(triphenylphosphine) palladium(0); diisopropylamine / toluene / 20 h / 80 °C / |Inert atmosphere View Scheme
参考文献
Mase, Nobuyuki; Ando, Taishi; Shibagaki, Fumiya; Sugita, Atsushi; Narumi, Tetsuo; Toda, Mitsuo; Watanabe, Naoharu; Tanaka, Fujie
Tetrahedron Letters, 2014 , vol. 55, # 11 p. 1946 - 1948
反应条件
boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone 1.) CHCl3, RT, 2.) CHCl3, RT; Yield given. Multistep reaction. Further byproducts given;
参考文献
Wagner, Richard W.; Johnson, Thomas E.; Lindsey, Jonathan S.
Journal of the American Chemical Society, 1996 , vol. 118, # 45 p. 11166 - 11180
