2-[(三甲基硅基)乙炔基]苯甲醛合成路线 （共 35 条）
反应条件
1.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C
1.2: 63 percent / tetrahydrofuran / 4 h / 20 °C
2.1: 95 percent / Bu4NF / tetrahydrofuran / 8 h / 26 °C
View Scheme
参考文献
Lopez-Carrillo, Veronica; Huguet, Nuria; Mosquera, Ungeles; Echavarren, Antonio M.
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10972 - 10978
反应条件
1.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C
1.2: tetrahydrofuran / 4 h / 20 °C
2.1: Bu4NF / tetrahydrofuran / 8 h / 26 °C
View Scheme
参考文献
Vasu, Dhananjayan; Hung, Hsiao-Hua; Bhunia, Sabyasachi; Gawade, Sagar Ashok; Das, Arindam; Liu, Rai-Shung
Angewandte Chemie - International Edition, 2011 , vol. 50, # 30 p. 6911 - 6914
反应条件
1: NaH / tetrahydrofuran / 12 h / 26 °C
2: Bu4NF / tetrahydrofuran / 10 h / 27 °C
3: 15 percent / TpRu(PPh3)(CH3CN)2PF6 / toluene / 6 h / 110 °C
View Scheme
参考文献
Shen, Hung-Chin; Pal, Sitaram; Lian, Jian-Jou; Liu, Rai-Shung
Journal of the American Chemical Society, 2003 , vol. 125, # 51 p. 15762 - 15763
反应条件
1: NaH / tetrahydrofuran / 12 h / 26 °C
2: Bu4NF / tetrahydrofuran / 10 h / 27 °C
3: 35 percent / TpRu(PPh3)(CH3CN)2PF6 / toluene / 6 h / 110 °C
View Scheme
参考文献
Shen, Hung-Chin; Pal, Sitaram; Lian, Jian-Jou; Liu, Rai-Shung
Journal of the American Chemical Society, 2003 , vol. 125, # 51 p. 15762 - 15763
反应条件
1: toluene-4-sulfonic acid / methanol / 4 h / 20 °C
2: potassium carbonate / methanol / 2 h / 20 °C
View Scheme
参考文献
Zi, Weiwei; Toste, F. Dean
Journal of the American Chemical Society, 2013 , vol. 135, # 34 p. 12600 - 12603
