(3aS,6aR)-1,3a,4,6a-四氢环戊烯并[c]呋喃-3-酮合成路线 (共 7 条)
反应条件
glycine-Na4P2O7 buffer; Sepharose-bound horse liver alhohol dehydrogenase; nicotinamide adenine dinucleotide; Flavin mononucleotide in water 22 h;
参考文献
Kajiwara, Tadahiko; Akakabe, Yoshihiko; Matsui, Kenji; Kodama, Kazuya; Koga, Harunobu; Nagakura, Takamitsu
Phytochemistry, 1997 , vol. 45, # 3 p. 529 - 532
反应条件
lithium iodide in N,N-dimethyl-formamide
2.5 h; Heating;
参考文献
Hudlicky, Tomas; Reddy, D. Bhaskar; Govindan, S. V.; Kulp, Thomas; Still, Bobbi; Sheth, Jagdish P.
Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3422 - 3428
反应条件
1: 74 percent / triethylamine, 4-(N,N-dimethylamino)pyridine / CH2Cl2 / 2 h / 22 °C
2: 62.2 percent / tosyl azide, triethylamine / acetonitrile / 36 h / Ambient temperature
3: 45.5 percent / CuSO4, Cu(acac)2 / benzene / 24 h / Heating
4: 28.8 percent / 580 - 600 °C / 0.01 Torr
5: 60.5 percent / LiI / dimethylformamide / 2.5 h / Heating
View Scheme
参考文献
Hudlicky, Tomas; Reddy, D. Bhaskar; Govindan, S. V.; Kulp, Thomas; Still, Bobbi; Sheth, Jagdish P.
Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3422 - 3428
反应条件
1: 62.2 percent / tosyl azide, triethylamine / acetonitrile / 36 h / Ambient temperature
2: 45.5 percent / CuSO4, Cu(acac)2 / benzene / 24 h / Heating
3: 28.8 percent / 580 - 600 °C / 0.01 Torr
4: 60.5 percent / LiI / dimethylformamide / 2.5 h / Heating
View Scheme
参考文献
Hudlicky, Tomas; Reddy, D. Bhaskar; Govindan, S. V.; Kulp, Thomas; Still, Bobbi; Sheth, Jagdish P.
Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3422 - 3428
反应条件
1: 45.5 percent / CuSO4, Cu(acac)2 / benzene / 24 h / Heating
2: 28.8 percent / 580 - 600 °C / 0.01 Torr
3: 60.5 percent / LiI / dimethylformamide / 2.5 h / Heating
View Scheme
参考文献
Hudlicky, Tomas; Reddy, D. Bhaskar; Govindan, S. V.; Kulp, Thomas; Still, Bobbi; Sheth, Jagdish P.
Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3422 - 3428
反应条件
1: 28.8 percent / 580 - 600 °C / 0.01 Torr
2: 60.5 percent / LiI / dimethylformamide / 2.5 h / Heating
View Scheme
参考文献
Hudlicky, Tomas; Reddy, D. Bhaskar; Govindan, S. V.; Kulp, Thomas; Still, Bobbi; Sheth, Jagdish P.
Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3422 - 3428
反应条件
Li[B(C6F5)4]*2.5(Et2O); dihydrogen peroxide; oxalic acid in 1,2-dichloro-ethane
T=20°C; Baeyer-Villiger Ketone Oxidation; 1 h; Catalytic behavior; Reagent/catalystTime; regioselective reaction;
参考文献
Uyanik, Muhammet; Nakashima, Daisuke; Ishihara, Kazuaki
Angewandte Chemie - International Edition, 2012 , vol. 51, # 36 p. 9093 - 9096
Angew. Chem., 2012 , vol. 124, # 36 p. 9227 - 9230,4