in benzene byproducts: HCl; addn. of half of theoretically necessary amount of H2S2 to a soln. of PCl3 in anhydrous benzene;; violent generation of HCl, small generation of H2S, product mixture obtained;;
in solid matrix Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PCl3=100:1:1 using unfiltered emission of Hg arc 20 K for 60 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Journal of Physical Chemistry, , vol. 89, # 15 p. 3326 - 3334
in neat (no solvent) passing a stream of H2S over a mixt. of PCl3 and PBr5;; product poluted with a small amount of bromine; removal of Br2 on shaking with Hg; fractionation at reduced pressure;;
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 224, p. 1422 - 1423
