in not given prepn. in laboratory; react. of Cl2 with PCl3; apparatus described;;
参考文献
Wazer, J. R. van
Encyclopedia of Chemical Technology, herausgegeben von Kirk, R. E., Othmer, D. F., The Interscience Encyclopedia, Inc., New York, Bd. 10, 1953, S. 479
aluminium trichloride in neat (no solvent) heating PCl3 with S and AlCl3 (catalyst) under exclusion of H2O; react. with the intermediate AlCl3*PCl3; addn. of AlCl3 in small portions to the boiling mixt. of PCl3 and S, react. on boiling completed after 10 min;; extraction of the cold crude product with H2O and separation with a separatory funnel; drying over CaCl2 and distn. at 125-126 °C at ambient pressure;;
参考文献
Knotz, F.
Oesterr. Chem. - Ztg., 1949 , vol. 50, p. 128 - 129
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Gmelin Handbook: P: MVol.C, 258, page 590 - 592
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Knotz, F.
Patent: US2915361 , 1959 ;
C. A., 1960 , p. 13579
