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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
77196-31-7
合成路线
(共 19 条)
67-56-1
甲醇
+
66-99-9
2-萘甲醛
→
反应条件
77196-31-7
反应条件
cobalt(II) 2-propyliminomethyl-phenolate functionalized mesoporous silica 2 h; Reflux;
参考文献
Rajabi
Journal of the Iranian Chemical Society, 2010 , vol. 7, # 3 p. 695 - 701
126644-23-3
→
反应条件
77196-31-7
反应条件
1: 45 percent / immobilized Burkholderia cepacia lipase; phosphate buffer; NaOH / decane; H2O / 38 h / 30 °C / pH 7.0 2: 75 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; dimethylformamide; hexane / 24 h / 30 °C / pH 6.0 3: 6 percent / nitrosylsulfuric acid / dimethylformamide / 0.5 h / 0 °C 4: Amberlyst-15 H+ form / 0.17 h View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
20862-03-7
→
反应条件
77196-31-7
反应条件
1: Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; ethanol / 18 h / 30 °C / pH 6.0 2: Amberlyst-15 H+ form / 0.17 h View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
126567-33-7
→
反应条件
77196-31-7
反应条件
1: 75 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; dimethylformamide; hexane / 24 h / 30 °C / pH 6.0 2: 6 percent / nitrosylsulfuric acid / dimethylformamide / 0.5 h / 0 °C 3: Amberlyst-15 H+ form / 0.17 h View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
475582-26-4
→
反应条件
77196-31-7
反应条件
1: 6 percent / nitrosylsulfuric acid / dimethylformamide / 0.5 h / 0 °C 2: Amberlyst-15 H+ form / 0.17 h View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
67-56-1
甲醇
+
827-54-3
2-乙烯基萘
→
反应条件
77196-31-7
+
66-99-9
2-萘甲醛
反应条件
pyridine-2-carboxylic acid; iron sulphate heptahydrate; dihydrogen peroxide T=20 - 60°C; 12 h; Schlenk techniqueMolecular sieve;
参考文献
Ray, Ritwika; Chowdhury, Abhishek Dutta; Lahiri, Goutam Kumar
ChemCatChem, 2013 , vol. 5, # 8 p. 2158 - 2161
35104-74-6
→
反应条件
77196-31-7
反应条件
1: basic peroxide oxidation 2: methanol / 40 °C / Irradiation View Scheme
参考文献
Ege, Seyhan N.; Gess, E. Joseph; Thomas, Anthony; Umrigar, Pesi; Griffin, Gary W.; et al.
Journal of the Chemical Society, Chemical Communications, 1980 , # 24 p. 1263 - 1265
77196-31-7
→
反应条件
156942-67-5
(R)-α-甲氧基-2-萘乙酸
反应条件
1.1: 1.69 g / SnBr2 / CH2Cl2 / 20 °C 2.1: 88 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; ethanol; hexane / 24 h / 30 °C / pH 6.0 3.1: 35 percent / nitrosylsulfuric acid / dimethylformamide / 24 h / 20 °C 4.1: SnBr2 / CH2Cl2 / 20 °C 4.2: 92 percent / CH2Cl2 / 20 °C 5.1: 45 percent / immobilized Burkholderia cepacia lipase; phosphate buffer; NaOH / decane; H2O / 38 h / 30 °C / pH 7.0 6.1: 75 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; dimethylformamide; hexane / 24 h / 30 °C / pH 6.0 7.1: nitrosylsulfuric acid / dimethylformamide / 0.5 h / 0 °C 8.1: 13.0 mg / CH2Cl2 9.1: 48 percent / silica gel / diethyl ether 10.1: 100 percent / Krebsiella oxytoca esterase; phosphate buffer / H2O / 39 °C / pH 7.0 View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
77196-31-7
→
反应条件
43210-73-7
(R)-2-(2-萘基)乙醇酸
反应条件
1.1: 1.69 g / SnBr2 / CH2Cl2 / 20 °C 2.1: 88 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; ethanol; hexane / 24 h / 30 °C / pH 6.0 3.1: 35 percent / nitrosylsulfuric acid / dimethylformamide / 24 h / 20 °C 4.1: SnBr2 / CH2Cl2 / 20 °C 4.2: 92 percent / CH2Cl2 / 20 °C 5.1: 45 percent / immobilized Burkholderia cepacia lipase; phosphate buffer; NaOH / decane; H2O / 38 h / 30 °C / pH 7.0 6.1: 75 percent / Rhodococcus rhodochrous IFO 15564; phosphate buffer / H2O; dimethylformamide; hexane / 24 h / 30 °C / pH 6.0 7.1: nitrosylsulfuric acid / dimethylformamide / 0.5 h / 0 °C View Scheme
参考文献
Kimura, Mayumi; Kuboki, Atsuhito; Sugai, Takeshi
Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1059 - 1068
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