2-Nitropropane; sodium in ethanol T=60 - 65°C; 2 h;

1: 89.6 percent / sodium methylate / ethanol; methanol / 5 h / Heating 2: 89.2 percent / phosphorus oxychloride, N,N-dimethylaniline / 1 h / Heating 3: 90.8 percent / methanol / 5 h / Heating 4: 71.7 percent / N-bromosuccinimide, dibenzoylperoxide, α,α'-azoisobutyronitrile / CCl4 / 3 h / Heating; Irradiation 5: 61 percent / sodium, 2-nitropropane / ethanol / 2 h / 60 - 65 °C View Scheme

1: 90.8 percent / methanol / 5 h / Heating 2: 71.7 percent / N-bromosuccinimide, dibenzoylperoxide, α,α'-azoisobutyronitrile / CCl4 / 3 h / Heating; Irradiation 3: 61 percent / sodium, 2-nitropropane / ethanol / 2 h / 60 - 65 °C View Scheme

1: 89.2 percent / phosphorus oxychloride, N,N-dimethylaniline / 1 h / Heating 2: 90.8 percent / methanol / 5 h / Heating 3: 71.7 percent / N-bromosuccinimide, dibenzoylperoxide, α,α'-azoisobutyronitrile / CCl4 / 3 h / Heating; Irradiation 4: 61 percent / sodium, 2-nitropropane / ethanol / 2 h / 60 - 65 °C View Scheme

1: 71.7 percent / N-bromosuccinimide, dibenzoylperoxide, α,α'-azoisobutyronitrile / CCl4 / 3 h / Heating; Irradiation 2: 61 percent / sodium, 2-nitropropane / ethanol / 2 h / 60 - 65 °C View Scheme