反应条件
aluminium in solid Ln2O3, AlBr3 (Ln:Al = 1:4) and Al powder were placed into an one-end sealed quartz tube under Ar, sealed under vac., heated at 600 K for 1 h; sealed tube was placed in a tubular furnace with a reduced temp. gradient from 750 to 460 K, vapor transport reaction for 6 h, tube was quickly removed from the furnace, the hot end was quenched with water, AlBr3 wascondensed;
参考文献
Wang, Zhi-Chang; Yu, Jin
Inorganic Chemistry, 2007 , vol. 46, # 10 p. 4248 - 4255
