三氯一氧化钒 三氯代氧化钒(V)合成路线 （共 117 条）
反应条件
in hexane
under N2; VOCl3 is added dropwise to a soln. of the starting complex inhexane at 0°C with stirring, cooled to -80°C, allowed to stand for 1 h; the solvent is decanted, the residue is washed, recrystd., elem. anal.;
参考文献
Preuss, Fritz; Towae, Willi
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981 , vol. 36, # 9 p. 1130 - 1135
反应条件
in benzene
under N2, stirred under reflux for 2 h; taken to dryness, filtered, washed with Et2O, dried under vac.; elem. anal.;
参考文献
Hills, Adrian; Hughes, David L.; Leigh, G. Geffery; Prieto-Alcon, Rafael
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 23 p. 3609 - 3618
反应条件
in acetonitrile
absence of air; stirring (room temp., 24 h); collection (filtration), washing (MeCN), crystn. (MeCN/CH2Cl2, -30°C); elem. anal.;
参考文献
Witt, M.; Roesky, H. W.
Polyhedron, 1989 , vol. 8, p. 1736 - 1741
反应条件
in neat (no solvent)
heating hexamethyldisiloxane;;
参考文献
Schmidt, M.; Schmidbaur, H.
Angewandte Chemie, 1959 , vol. 71, p. 220 - 220
反应条件
moisture in neat (no solvent)
参考文献
Berzelius, J. J.
Annalen der Physik (Weinheim, Germany), 1831 , vol. 22, p. 1 - 67
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Gmelin Handbook: V: MVol.B1, 90, page 243 - 246
反应条件
in tetrachloromethane
参考文献
Seifert, H. J.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1962 , vol. 317, p. 123 - 128
反应条件
in not given
by reflux;;
参考文献
Seifert, H. J.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1962 , vol. 317, p. 123 - 128
参考文献
Wegelin, G.
Z. Chem. Ind. Kolloide, 1912 , vol. 11, p. 25 - 28
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Gmelin Handbook: V: MVol.B1, 90, page 243 - 246
反应条件
nitrogen in neat (no solvent)
at 0°C;;
参考文献
Gmelin Handbook: V: MVol.B1, 90, page 243 - 246
反应条件
in not given
mixing at -195°C; reaction at ambiente temp.; complete rection in closed tube at 60°C about 72 h;; removing of Cl2 at -40°C; destillation of vanadylfluorosulfate;;
参考文献
Kleinkoff, G. C.; Shreeve, J. M.
Inorganic Chemistry, 1964 , vol. 3, p. 607 - 609
