1: With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; palladium diacetate in toluene T=80°C; 2: With water; acetic acid in tetrahydrofuran
参考文献
Willis, Michael C.; Brace, Gareth N.
Tetrahedron Letters, 2002 , vol. 43, # 50 p. 9085 - 9088
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 3 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
