water in water Kinetics; byproducts: H(1+); at 25°C +/-0.1°C, ionic strength 0.5 M (NaClO4); not isolated; monitoring by UV (360 nm), pH and redox potential measurements;
参考文献
Journal of Physical Chemistry, , vol. 96, # 14 p. 5852 - 5856
in water
Kinetics; decompn. of NaClO2 soln. at pH = 9.2 - 9.7 at 102 - 104°C or at 82 - 84°C and 350 Torr or at 53 - 54°C and 98 Torr; no influence of NaCl;;
参考文献
Zdilla, Michael J.; Lee, Amanda Q.; Abu-Omar, Mahdi M.
Inorganic Chemistry, 2009 , vol. 48, # 5 p. 2260 - 2268
phosphate buffer; NaClO4 in water
Kinetics; oxidn. of NaClO2 by HOCl in distd. water in the presence of phosphate buffer; 25°C; ionic strength 1.0 M (NaClO4); pH 5.0-8.0; rate constant depended on ClO2(1-) concn., pH, buffer concn.; not isolated;
参考文献
Jia, Zhongjiang; Margerum, Dale W.; Francisco, Joseph S.
Inorganic Chemistry, 2000 , vol. 39, # 12 p. 2614 - 2620
