sodium hydroxide in water
Kinetics; effect of chemical composition in the acid-catalysed reaction investigated at 25 °C in a Hele-Shaw cell with Plexiglass walls; not isolated;
参考文献
Bansagi Jr., Tamas; Horvath, Dezso; Toth, Agota
Chemical Physics Letters, 2004 , vol. 384, # 1-3 p. 153 - 156
sodium hydroxide; sodium acetate in water
Kinetics; byproducts: H(1+); hydrogel soaking with reactants soln. (NaOH add. to eliminate self-initiation, CH3COONa addn. to keep const. pH-drop in reaction fronts), gel cutting in two, smaller part rinsing in dil H2SO4; reaction front monitoring with monochrome CCD camera;
参考文献
Horvath, Dezso; Toth, Agota
Journal of Chemical Physics, 1998 , vol. 108, # 4 p. 1447 - 1451
water in water
Kinetics; byproducts: H(1+); at 25°C +/-0.1°C, ionic strength 0.5 M (NaClO4); not isolated; monitoring by UV (360 nm), pH and redox potential measurements;
参考文献
Epstein, Irving R.; Kustin, Kenneth; Simoyi, Reuben H.
Journal of Physical Chemistry, 1992 , vol. 96, # 14 p. 5852 - 5856
