in gaseous matrix Irradiation (UV/VIS); laser ablation of metal, co-deposition with Ar or Ne containing CDF3 at 4 K, photolysis with Hg lamp (175 W); not isolated, detected by IR;
in melt heating Al in a melt of CeF3 to 1000°C, react. stops when Al contents 1.5percent Ce;;
参考文献
Gmelin Handbook: Al: MVol.A2, 34, page 346 - 347
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Borchert, W.; Barth, O.
Patent: DE246484 , 1911 ;
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反应条件
in neat (no solvent) byproducts: LiF, CeH2; (LiBH4+1/3CeF3) mixt. (ball milled for 1-48 h) evacuated to 1E-3 Torr, heated at rate 2°C/min from room temp. to 450-600°C; DSC-TG-MS, XRD;
参考文献
Journal of Alloys and Compounds, , vol. 509, # 3 p. 751 - 757
in neat (no solvent) in streaming Cl2-gas at 200-300°C;;
参考文献
Beloborodova, L. G.; Simkina, L. V.; Serebrennikov, V. V.
Tr. Tomsk. Univ., 1971 , vol. 204, p. 82 - 85
C. A., 1973 , vol. 78, p. 131489
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Gmelin Handbook: Sc: MVol.C3, 6.2.2.9.3.3, page 110 - 110
