sodium hydride in dimethyl sulfoxide; paraffin 3 h;

1: 26 percent / sodium hydride / paraffin; dimethylsulfoxide / 3 h 2: 4.45 g / aq. sodium hydroxide / 0.5 h / Heating 3: 1.19 g / tetrahydrothiophene 1,1-dioxide / heating, then distilling View Scheme

water Ambient temperatureacetate buffer (pH 4.2); enaminal hydrolysis; stereochemistry and kinetics of formation of enaminals from reactions of malondialdehydes with various amino acids; Rate constantEquilibrium constant;

1: 26 percent / sodium hydride / paraffin; dimethylsulfoxide / 3 h 2: 4.45 g / aq. sodium hydroxide / 0.5 h / Heating View Scheme

water Ambient temperatureacetate buffer (pH 4.2); enaminal hydrolysis; stereochemistry and kinetics of formation of enaminals from reactions of malondialdehydes with various amino acids; Rate constantEquilibrium constant;