1-甲基-2,2-二苯基乙烯合成路线 (共 153 条)
反应条件
n-butyllithium
1.) THF, hexane, -78 deg C, 45 min, 2.) THF, hexane, -78 deg C, 60 min; Yield given. Multistep reaction;
参考文献
Hanessian, Stephen; Bennani, Youssef L.; Leblanc, Yves
Heterocycles, 1993 , vol. 35, # 2 p. 1411 - 1424
反应条件
methyllithium; tert.-butyl lithium
1.) THF, ether, -100 deg C, 2 h, 2.) ether, pentane, -100 deg C, 3 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Maercker, Adalbert; Boes, Benno; Hajgholipour, Mohammad Taghi
Journal of Organometallic Chemistry, 1998 , vol. 566, # 1-2 p. 143 - 149
反应条件
pyridine; copper diacetate
T=5°C; Irradiationinvestigation effect of present or absent of pyridine and various Cu(II) salts; Product distribution;
参考文献
Kitamura, Tsugio; Kobayashi, Shinjiro; Taniguchi, Hiroshi
Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2641 - 2645
反应条件
in diethyl ether; hexane
T=20°C; 1 h; with various additive and solvents; Product distribution;
参考文献
Tanaka, Jiro; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the American Chemical Society, 1987 , vol. 109, # 11 p. 3391 - 3397
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; n-butyllithium; N,N,N',N,-tetramethylethylenediamine; 1-methyl-5-hexenyl bromide
2.) Et2O, hexane, 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tanaka, Jiro; Morishita, Hiroaki; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1009 - 1014
反应条件
n-butyllithium
Yield given. Multistep reaction;
参考文献
Cristau; Taillefer; Urbani; Fruchier
Tetrahedron, 1996 , vol. 52, # 6 p. 2005 - 2020
反应条件
Yield given. Multistep reaction;
参考文献
Beak, Peter; Becker, Peter D.
Journal of Organic Chemistry, 1982 , vol. 47, # 20 p. 3855 - 3861
参考文献
Ando, Wataru; Tanikawa, Hirohide; Sekiguchi, Akira
Tetrahedron Letters, 1983 , vol. 24, # 39 p. 4245 - 4248
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; n-butyllithium; N,N,N',N,-tetramethylethylenediamine
2.) Et2O, hexane, 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tanaka, Jiro; Morishita, Hiroaki; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1009 - 1014
反应条件
in 2-methyl cyclohexane
Ambient temperatureIrradiationother temperature; Product distribution;
参考文献
Tomioka, Hideo; Ueda, Hiroaki; Kondo, Shingo; Izawa, Yasuji
Journal of the American Chemical Society, 1980 , vol. 102, # 26 p. 7817 - 7818