1-甲基-2,2-二苯基乙烯合成路线 （共 153 条）
反应条件
1: With bromine in 1,2-dichloro-ethane
T=20°C; 1 h;
2: With pyridine in 1,2-dichloro-ethane; toluene
T=80°C; 3 h; Further stages.;
参考文献
Suzuki, Ken; Hori, Yoji; Nishikawa, Takenobu; Kobayashi, Tohru
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 13 p. 2089 - 2091
反应条件
pyridine; bromine in toluene
参考文献
Suzuki, Ken; Kobayashi, Tohru; Nishikawa, Takenobu; Hori, Yoji; Hagiwara, Toshimitsu
Patent: US2002/58837 A1, 2002 ;
反应条件
1: chlor / acetic acid
2: 1.50 g / acetic acid / 2 h / Heating
View Scheme
参考文献
Perrot
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1936 , vol. 202, p. 494
参考文献
Temnikowa et al.
Sb. Statei Obshch. Khim., 1953 , p. 874,876
Chem.Abstr., 1955 , p. 6889
反应条件
1: 50percent aq. NaOH, triethylbenzylammonium chloride / 7 h / 40 - 45 °C
2: 55 percent / m-xylene / 25 h / 139 °C
View Scheme
参考文献
Kostikov, R. R.; Varakin, G. S.; Ogloblin, K. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, # 8 p. 1438 - 1444
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1625 - 1632
反应条件
1: 50percent aq. NaOH, triethylbenzylammonium chloride / hexane; ethanol / 12 h / 40 - 45 °C
2: 72 percent / p-toluenesulfonic acid / m-xylene / 3 h / 139 °C
View Scheme
参考文献
Kostikov, R. R.; Varakin, G. S.; Ogloblin, K. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, # 8 p. 1438 - 1444
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1625 - 1632
反应条件
N-bromosuccinmide in tetrachloromethane
参考文献
Novo Nordisk A/S
Patent: US5198451 A1, 1993 ;
反应条件
N-bromosuccinmide; dibenzoyl peroxide in tetrachloromethane
12 h; Reflux;
参考文献
Ito, Yosuke; Jogo, Shunsuke; Fukuda, Noriko; Okumura, Ryo; Nishino, Hiroshi
Synthesis, 2011 , # 9 art. no. F16411SS, p. 1365 - 1374
参考文献
Novo Nordisk A/S
Patent: US6174898 B1, 2001 ;
反应条件
tetrachloromethane; dibenzoyl peroxide
参考文献
Bonafede
Rev. Fac. Cienc. quim. Univ. La Plata, 1955 , vol. 29, p. 41,45
