4-氰基-3-硝基三氟甲基苯合成路线 （共 30 条）
反应条件
lithium bromide in tetrahydrofuran T=130°C; 6 h; Product distribution / selectivity;
参考文献
Bayer CropScience S.A.
Patent: US6635780 B1, 2003 ;
Location in patent: Page/Page column 9 ;
反应条件
copper(I) bromide; (benzyl)-tri-(methyl)-ammonium bromide in acetonitrile T=20 - 160°C; 8 h; Product distribution / selectivity;
参考文献
Bayer CropScience S.A.
Patent: US6635780 B1, 2003 ;
Location in patent: Page/Page column 8 ;
反应条件
lithium bromide in acetonitrile T=110°C; 18 h; Product distribution / selectivity;
参考文献
Bayer CropScience S.A.
Patent: US6635780 B1, 2003 ;
Location in patent: Page/Page column 10 ;
反应条件
in 1-methyl-pyrrolidin-2-one T=130°C; 4 h;
参考文献
DILLARD, Lawrence W.; YUAN, Jing; LEFTHERIS, Katerina; VENKATRAMAN, Shankar; WU, Guosheng; JIA, Lanqi; XU, Zhenrong; CACATIAN, Salvacion; MORALES-RAMOS, Angel; SINGH, Suresh; ZHENG, Yajun
Patent: WO2011/106414 A1, 2011 ;
Location in patent: Page/Page column 74 ;
WO 2011/106414 A1
反应条件
tetrabutylammomium bromide in acetonitrile T=20 - 80°C; 13 h; Product distribution / selectivity;
参考文献
Bayer CropScience S.A.
Patent: US6635780 B1, 2003 ;
Location in patent: Page/Page column 7 ;
反应条件
pyridine; hydrogenchloride; bromine; iron(III) chloride in N-methyl-acetamide; water
反应条件
hydrogenchloride; sodium nitrite in water
反应条件
tetra-n-butylammonium tetrafluoroborate in N,N-dimethyl-formamide T=10°C; Electrolysis;
参考文献
Gallardo, Iluminada; Guirado, Gonzalo; Marquet, Jordi
Journal of Organic Chemistry, 2002 , vol. 67, # 8 p. 2548 - 2555
反应条件
in acetonitrile T=20 - 80°C; 6 h; Product distribution / selectivity;
参考文献
Bayer CropScience S.A.
Patent: US6635780 B1, 2003 ;
Location in patent: Page/Page column 6-7 ;
