in neat (no solvent) reaction of CsF and ClF3 at 80°C about 4 h; condensation of F2 to CsClF4; heating 22 h at 150°C; removing of excess F2; apparatus described;; distillation of ClF5;;
参考文献
Pilipovich, D.; Maya, W.; Lawton, E. A.; Bauer, H. F.; Sheehan, D. F.; et al.
Inorganic Chemistry, 1967 , vol. 6, p. 1918 - 1919
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Gmelin Handbook: Cl: SVol.B2, 121, page 573 - 575
in gas Kinetics; investigation of react. in a fast-flow system; (generation of SiF2 fromSiF4 or Si2F6);; measurement of first-order decays of SiF2 using laser-induced fluorescence detection;;
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Stanton, A. C.; Freedman, A.; Wormhoudt, J.; Gaspar, P. P.
Chemical Physics Letters, 1985 , vol. 122, p. 190 - 195
in solid matrix byproducts: SiHD3; Irradiation (UV/VIS); dilg. SiD4 with Ar (various ratios); codeposition with F2 dild. with Ar (various ratios) on a substrate at 13.+-1. K; UV-photolysis (220-1000 nm) for 1 h; annealing to 25.+-.2 K;; not isolated, identified by IR-spectroscopy; further products;;
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McInnis, Thomas C.; Andrews, Lester
Journal of Physical Chemistry, 1992 , vol. 96, # 13 p. 5276 - 5284
in solid matrix byproducts: HF, H2O, O2F; Irradiation (UV/VIS); dilg. SiH4 with Ar (various ratios); codeposition with F2 dild. with Ar (various ratios) on a substrate at 13.+-1. K; UV-photolysis (220-1000 nm) for 1 h; annealing to 25.+-.2 K;; not isolated, identified by IR-spectroscopy; further products;;
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McInnis, Thomas C.; Andrews, Lester
Journal of Physical Chemistry, 1992 , vol. 96, # 13 p. 5276 - 5284
Kinetics; Special app., reduced pressure, thermal etching of p-doped silicon(110) single crystals by F2 (10percent in helium) at surface temp. between 300 and 1200 K, dependence on temp. and pressure and react. mechanism discussed.; Monitored by MPI/MS and EI/MS.;
参考文献
Squire, D. W.; Dagata, J. A.; Hsu, D. S. Y.; Dulcey, C. S.; Lin, M. C.
Journal of Physical Chemistry, 1988 , vol. 92, # 10 p. 2827 - 2834
in neat (no solvent) fluorination (N2 carrier gas (ratio F/N2 1:5), -30°C, 2 h);
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Padma, D K; Kalbandkeri, R G; Suresh, B S; Bhat, V Subrahmanya
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1991 , vol. 30, # 2 p. 172 - 176
