in neat (no solvent)
WTe2 placed in a tungsten saucer, addn. of a small amt. of sulfur as fuse, react. with fluorine in a prefluorinated perforated nickel crucible;
参考文献
O'Hare, P. A. G.; Hope, G. A.
Journal of Chemical Thermodynamics, 1992 , vol. 24, # 6 p. 639 - 647
in neat (no solvent)
High Pressure; TeFCl5 (5.81 mmol) was allowed to react with F2 (23.2 mmol) for 3 d at 165°C in a Parr bomb;; detected by IR-, Raman and NMR-expt.;
参考文献
Lawlor, Lawrence J.; Passmore, Jack
Canadian Journal of Chemistry, 1984 , vol. 62, p. 1477 - 1482
in neat (no solvent)
Ensemble of MoTe2 on W-saucer with small quantities of S, resting on a perfluorinated Ni-crucible, is combusted with F2 in a calorimeter bomb.; Gases are condensed into a trap (liq. N2).;
参考文献
O'Hare, P. A. G.; Hope, G. A.
Journal of Chemical Thermodynamics, 1989 , vol. 21, # 7 p. 701 - 708
in neat (no solvent)
As purified by heating at 210°C under vac. for 2 d, stoich. amt.of F2 reacted with As powder at -196°C, heated at 150°C for 8 h; AsF5 rapidly vac. distd. at room temp., then product distd. in vac. onto excess NaF;
参考文献
Sawyer, Jeffery F.; Schrobilgen, Gary J.; Sutherland, Steven J.
Inorganic Chemistry, 1982 , vol. 21, p. 4064 - 4072
