in neat (no solvent)
Kinetics; HO2 reacted with OCl at 220-336 K in He carrier gas at 1.5 Torr;
参考文献
Burrows, John P.; Cox, Richard A.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , vol. 77, p. 2465 - 2480
in gas
Kinetics; discharge flow; molecular beam mass spectrometer;
参考文献
Elrod, Matthew J.; Meads, Roger F.; Lipson, Jennifer B.; Seeley, John V.; Molina, Mario J.
Journal of Physical Chemistry, 1996 , vol. 100, # 14 p. 5808 - 5812
→
反应条件
in neat (no solvent, gas phase)
Kinetics; at 200-700 K; not isolated, detected by mass spectrometry;
参考文献
Midey, Anthony; Dotan, Itzhak; Viggiano
Journal of Physical Chemistry A, 2008 , vol. 112, # 14 p. 3040 - 3045
in neat (no solvent, gas phase)
Kinetics; Irradiation (UV/VIS); pulsed photolysis-resonant fluorescence; 210-370 K; detection of: NO by chemiluminescence, NO2 and O3 by diode array spect.,N2O by FTIR spect.;
in gaseous matrix
Kinetics; reacting HO2 radicals with NF2 at 300 - 610 K at a pressure of 10.2 - 12.9 mmHg (He atmosphere, fast flow apparatus, quartz reactor); ESR/LRM IR spectrometry;
参考文献
Rozenshtein, V. B.; Bedzhanyan, Yu. R.
Kinetics and Catalysis, 1988 , vol. 29, p. 268 - 272
Kinetika i Kataliz, 1988 , vol. 29, p. 311 - 315
Cl2 in gaseous matrix
byproducts: CH2O, CH2O; Irradiation (UV/VIS); photolysis Cl2-CH3OH-O2-Cl2O mixt. with N2 as the bath gas; detected by UV spectra;
参考文献
Nickolaisen, Scott L.; Roehl, Coleen M.; Blakeley, Lisa K.; Friedl, Randall R.; Francisco, Joseph S.; Liu, Ruifeng; Sander, Stanley P.
Journal of Physical Chemistry A, 2000 , vol. 104, # 2 p. 308 - 319
