byproducts: H2; in presence of AlBr3;; not isolated;;
参考文献
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2326 - 2326
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Gmelin Handbook: Ge: MVol., 17, page 49 - 51
F in neat (no solvent) byproducts: GeH3, GeH2, Ge; other Radiation; production of atomic fluorine by microwave discharge through mixt. of F2 in helium; react. with GeH4 in flow cell described; IR spectroscopy;;
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Brown, John M.; Evenson, K. M.; Sears, Trevor J.
Journal of Chemical Physics, 1985 , vol. 83, # 7 p. 3275 - 3284
AlCl3 congealing of the products; pumping H2 out; fractionating; transition temp.: -135 - -120 °C (GeH4), -120 - -90 °C (HCl), -83 - -78 °C (H3GeCl) and -61 - -52 °C (H2GeCl2);;
参考文献
Smyth, C. P.
Journal of the American Chemical Society, 1941 , vol. 63, p. 57 - 66
in neat (no solvent) reaction with SnCl4 at room temp. under formation of GeH3Cl; no GeH2Cl2 formed;;
参考文献
Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V.
Inorganic and Nuclear Chemistry Letters, 1971 , vol. 7, p. 1077 - 1079
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Gmelin Handbook: Sn: MVol.C1, 6.9.7.5.10, page 311 - 311
