in neat (no solvent)
reaction with SnCl4 at room temp. under formation of GeH3Cl; no GeH2Cl2 formed;;
参考文献
Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V.
Inorganic and Nuclear Chemistry Letters, 1971 , vol. 7, p. 1077 - 1079
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Gmelin Handbook: Sn: MVol.C1, 6.9.7.5.10, page 311 - 311
Blake, Alexander J.; Cradock, Stephen; Franklin, Keith C.; Fraser, Stuart G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 1663 - 1668
Mackay, K. M.; Robinson, P.; Spanier, E. J.; MacDiarmid, A. G.
Journal of Inorganic and Nuclear Chemistry, 1966 , vol. 28, p. 1377 - 1384
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Gmelin Handbook: Ag: MVol.B2, 7.2.8.7.2, page 114 - 114
Mackay, K. M.; Robinson, P.; Spanier, E. J.; MacDiarmid, A. G.
Journal of Inorganic and Nuclear Chemistry, 1966 , vol. 28, p. 1377 - 1384
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Gmelin Handbook: Ag: MVol.B2, 7.2.8.7.2, page 114 - 114
in gaseous matrix
Kinetics; byproducts: GeH3; (Ar); react. of Cl atoms (generated by microwave discharge of Cl2) andGeH4 at room temp. in an Ar flow at 0.7 torr within ca. 0.3 ms; not isolated, detected by IR chemiluminescence;
参考文献
Wickramaaratchi, M. A.; Setser, D. W.
Journal of Physical Chemistry, 1983 , vol. 87, # 1 p. 64 - 72
