in neat (no solvent) from CHI3 and Si4H10 at room temp. for a period of days;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1946 , p. 1131 - 1134
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Gmelin Handbook: Si: MVol.B, 273, page 735 - 739
in neat (no solvent)
SiH4 passed through a glass ozonator, higher silanes condensed in a trap held at -131°C; Si2H6 removed by raising the temp. to -95°C, trapping, mixture holding at -63°C, trapping (Si3H8 removed), mixture holding at -29°C, trapping (Si4H10);
参考文献
Perkins, G. G. A.; Lampe, F. W.
Journal of the American Chemical Society, 1980 , vol. 102, # 11 p. 3764 - 3769
Hg in neat (no solvent, gas phase)
Irradiation (UV/VIS); The mixt. of silane, H2 and mercury vapor was illuminated by the partially collimated beam of a low-pressure mercury resonance lamp;; cooled to liquid-N2 temp., H2 pumped off, identified by mass spect.;;
参考文献
Olbrich, G.; Potzinger, P.; Reimann, B.; Walsh, R.
Organometallics, 1984 , vol. 3, p. 1267 - 1272
