trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent)
参考文献
Moissan, H.
Ann. chim. Phys. (6), 1890 , vol. 19, p. 286 - 288
反应条件
in not given
byproducts: (PCl4)(SbCl6); vigorous react. of PCl3 with SbCl4F;;
参考文献
Kolditz, L.
Z. anorg. allg. Chem., 1957 , vol. 289, p. 128 - 140
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in not given
byproducts: KCl, SO2; fluorination of PCl3 with KSO2F;;
参考文献
Seel, F.; Riehl, L.
Z. anorg. allg. Chem., 1955 , vol. 282, p. 293 - 306
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
heating PCl3 with SnF4 in a sealed tube;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
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Wolter, L.
Diss. Berlin 1908, S. 1/55
反应条件
in not given
byproducts: MoCl5, PCl5; react. of PCl3 with MoF6;;
参考文献
O'Donnell, T. A.; Stewart, D. F.
Journal of Inorganic and Nuclear Chemistry, 1962 , vol. 24, p. 309 - 314
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
react. of PCl3 with C6H5COF at 140°C;;
参考文献
Seel, F.; Ballreich, K.; Peters, W.
Chemische Berichte, 1959 , vol. 92, p. 2117 - 2122
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in further solvent(s)
dissolving PCl5 in AsCl3; addn. of AsF3 drop by drop; pptn. on cooling, evolution of PF3 after completation of react.;; isolation of ppt., washing with AsCl3, removal of AsCl3 by a stream of air;;
参考文献
Kolditz, L.
Z. Anorg. Chem., 1956 , vol. 284, p. 144 - 152
反应条件
in not given
react. of an excess of PCl3 with MoF6 forming PF3, MoCl5, Cl2; further react. of an excess of PCl3 with Cl2 forming PCl5;;
参考文献
O'Donnell, T. A.; Stewart, D. F.
Journal of Inorganic and Nuclear Chemistry, 1962 , vol. 24, p. 309 - 314
反应条件
in not given
fluorination of P2I2 with SbF5;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
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Harris, G. S.
Payne, D. S. (Quart. Rev. 15 (1961) 173/89)
反应条件
in neat (no solvent)
100°C (7 h); cis-trans isomery detected by NMR;
参考文献
Cavell,R.G.; Nixon,J.F.
Proceedings of the Chemical Society, London, 1964 , p. 229
