trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent) excess of PF3 condensed onto OsF6 at -196°C, allowed to warm slowly to room temp.; volatiles species removed, fractionated; IR;
参考文献
Burns, R. C.; O'Donnell, T. A.
Journal of Inorganic and Nuclear Chemistry, 1980 , vol. 42, p. 1285 - 1292
反应条件
in neat (no solvent) excess of PF3 condensed onto IrF6 at -196°C, allowed to warm slowly to room temp.; volatiles species removed, fractionated; IR;
参考文献
Burns, R. C.; O'Donnell, T. A.
Journal of Inorganic and Nuclear Chemistry, 1980 , vol. 42, p. 1285 - 1292
反应条件
in hydrogen fluoride HF (liquid); IrF6 dissolved in anhydrous HF, cooled the Kel-F-tube to -196°C, PF3 added, tube placed in an acetone-solid CO2 cold bath, maintained for a long period at -78°C, allowed to warm to room temp. for 12 h; votlatile species removed, fractionation; elem. anal.; IR;
参考文献
Burns, R. C.; O'Donnell, T. A.
Journal of Inorganic and Nuclear Chemistry, 1980 , vol. 42, p. 1285 - 1292
反应条件
in not given fast react. of PF3 with Cl2 forming PF3Cl2; slow react. of PF3Cl2 forming (PCl4)(PF6) and slow react. forming PCl5 and PF5;; solid (PCl4)(PF6) contains small amounts of PCl5 or PFCl4;;
参考文献
Gmelin Handbook: P: MVol.C, 211, page 484 - 487
反应条件
in further solvent(s) PF3 condenced into soln. SbF5 in AsF3 and allowed to stand for 3 h at room temp.; volatiles removed;
参考文献
Nandana, W. A. Shantha; Passmore, Jack; Swindells, D. C. Neil; Taylor, Peter; White, Peter S.; Vekris, John E.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 619 - 626
反应条件
in hydrogen fluoride HF (liquid); OsF6 dissolved in anhydrous HF, cooled the Kel-F-tube to -196°C, PF3 added, tube placed in an acetone-solid CO2 cold bath, maintained for a long period at -78°C, allowed to warm to room temp. for 12 h; votlatile species removed, fractionation; elem. anal.; IR;
参考文献
Burns, R. C.; O'Donnell, T. A.
Journal of Inorganic and Nuclear Chemistry, 1980 , vol. 42, p. 1285 - 1292
反应条件
in not given fast react. of PF3 with Cl2 forming PF3Cl2; slow react. of PF3Cl2 forming (PCl4)(PF6) and slow react. forming PCl5 and PF5;; solid (PCl4)(PF6) contains small amounts of PCl5 or PFCl4;;
参考文献
Gmelin Handbook: P: MVol.C, 211, page 484 - 487
反应条件
in solid matrix Irradiation (UV/VIS); reaction of titanium ablated atoms with phosphorus trifluoride in Ar with condensation at 8 K for 60 min, irradiation at 290 mn for 20 min, irradiation at >220 nm for 20 min; IR monitoring;
参考文献
Wang, Xuefeng; Lyon, Jonathan T.; Andrews, Lester
Inorganic Chemistry, 2009 , vol. 48, # 13 p. 6297 - 6302
反应条件
in neat (no solvent) react. of C with PF3 in a Ni-tube at 1100°C;;
参考文献
US2709186 , ;
C. A., , p. 6499
反应条件
in gas Kinetics; discharge-flow apparatus: passing PF3 dild. in Ar through rf discharge;admission of HN3 (in He) to the flow via injector;; not isolated; detn. by chemiluminescence;;
参考文献
Henshaw, T. L.; MacDonald, M. A.; Stedman, D. H.; Coombe, R. D.
Journal of Physical Chemistry, 1987 , vol. 91, # 11 p. 2838 - 2842
