trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent) react. with KF at 150°C;;
参考文献
Gmelin Handbook: P: MVol.C, 171, page 393 - 395
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Muetterties, E. L.; Bither, T. A.; Farlow, M. W.; Coffman, D. D.
J. inorgan. nuclear Chem., 1960 , vol. 16, p. 52 - 59
反应条件
in solid matrix byproducts: S[PF3](n); Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PF3=100:1:1 using unfiltered emissionof Hg arc for 55 min at 20 K; with or without annealing matrix to 38 K for 10 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
反应条件
antimony pentachloride in neat (no solvent)
byproducts: PF2Cl, PFCl2; react. of PCl3 with SbF3 at 40°C in presence of SbCl5 as catalyst;; generation of a gas contg. 80-90percent PF3;;
参考文献
Booth, H. S.; Bozarth, A. R.
Journal of the American Chemical Society, 1933 , vol. 55, p. 3890 - 3890
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in not given
byproducts: PF2Br, PFBr2; fluorination of PBr3 with SbF3 at 80°C;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
sodium chloride in neat (no solvent)
byproducts: POF3, POCl3, POFCl2; heating a mixt. of CaF2 and NaCl with P2O5 at 350-600°C; formation of PF3, POF3, POCl3, POFCl2, POF2Cl and HCl;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
参考文献
Krause, L. J.; Morrison, J. A.
Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 2995 - 3001
反应条件
Fe in neat (no solvent)
redn. by Fe at 600.degreee.C;;
参考文献
Tarbutton, G.; Egan, E. P.; Frary, S. G.
Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789
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Gmelin Handbook: P: MVol.C, 175, page 403 - 404
反应条件
antimony pentachloride in not given
react. of PClF2 with SbF3 in presence of SbCl5 as catalyst at -50- -55°C and 720 torr;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
heating P2O5 with CaF2 at 500-1000°C;;
参考文献
Tarbutton, G.; Egan, E. P.; Frary, S. G.
Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789
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Gmelin Handbook: P: MVol.C, 174, page 399 - 403
反应条件
in neat (no solvent)
dropwise addn. of AsF3 to PCl3 in absence of H2O;; washing the PF3 with H2O, H2SO4 and with a pumice impregnated with H2SO4;;
参考文献
Moissan, H.
C. r. Acad. Sci. (Paris), 1885 , vol. 100, p. 272 - 275
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
