trifluorophosphane合成路线 （共 187 条）
反应条件
byproducts: CO; 14 d, 250°C; complete decompn.;
参考文献
Griffiths, J. E.; Burg, A. B.
Journal of the American Chemical Society, 1960 , vol. 82, p. 1507 - 1508
反应条件
antimony(V) pentachloride in neat (no solvent)
react. of PCl3 with SbF3; formation of PF2Cl, PFCl2, PF3; catalyst SbCl5;;
参考文献
Booth, H. S.; Bozarth, A. R.
Journal of the American Chemical Society, 1933 , vol. 55, p. 3890 - 3890
反应条件
bromine in neat (no solvent)
fluorination of PBr3 with SbF3 using Br2 as catalyst;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
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Gmelin Handbook: P: MVol.C, 222, page 509 - 511
反应条件
in neat (no solvent)
byproducts: phosphorus fluoride chloride; react. of PCl5 with SbF3;;
参考文献
Booth, H. S.; Swinehart, C. F.
Journal of the American Chemical Society, 1932 , vol. 54, p. 4751 - 4753
反应条件
in neat (no solvent)
byproducts: PBr3; decompn. on storage;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
byproducts: PBr3; decompn. on storage;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
thermal decompn. of (Cf3)2POP(CF3)2 during 14 days at 250°C;;
参考文献
Griffiths, J. E.; Burg, A. B.
Journal of the American Chemical Society, 1960 , vol. 82, p. 1507 - 1508
View citing articles Show Details
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in not given
byproducts: PFBr2, PF2Br; fluorination of PBr3 with CaF2;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
partial decomposition on standing;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
View citing articles Show Details
Gmelin Handbook: P: MVol.C, 222, page 509 - 511
反应条件
in neat (no solvent)
byproducts: PF5; react. of solid PCl5 with SbF3;;
参考文献
Booth, H. S.; Swinehart, C. F.
Journal of the American Chemical Society, 1932 , vol. 54, p. 4751 - 4753
View citing articles Show Details
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
