trifluorophosphane合成路线 （共 187 条）
反应条件
in gas
byproducts: NiC6H5CHCH2(1+), NiC6H5COCH3(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
反应条件
in neat (no solvent)
addn. of 80 g SbF3 to a mixt. of 200 g POCl3 and 50 g SbCl5 at 75 °C and 190-200 Torr;; products contains 55 percent PF3, 5 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
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Gmelin Handbook: P: MVol.C, 212, page 487 - 489
反应条件
carbon in neat (no solvent)
byproducts: CF4; Electric Arc; react. of PF5 with C in the electric arc;;
参考文献
E. I. du Pont de Nemours & Co.
Patent: DE1038535 , 1958 ;
C. A., 1961 , p. 3249
反应条件
in neat (no solvent)
heating with CaF2 in presence of NaCl;;
参考文献
Gmelin Handbook: Ca: MVol.B2, 67, page 419 - 421
反应条件
byproducts: HCl; at room temp.;
参考文献
Ruff, O.; Graf, H.; Heller, W.; Knoch
Ber., 1906 , vol. 39, p. 4314
反应条件
in neat (no solvent)
byproducts: POF3, POCl3, HCl; heating P2O5, NaCl and CaF2 at 350-400 °C; ratio of products depending on mixing ratio of educts;; isolation from PF3, POF3, POCl3 and HCl by fractional distn.;;
参考文献
Tarbutton, G.; Egan, E. P.; Frary, S. G.
Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789
反应条件
H2 in neat (no solvent)
react. with H2 at 250 °C;;
参考文献
Poulenc, C.
Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570
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Poulenc, C.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78
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Gmelin Handbook: P: MVol.C, 211, page 484 - 487
反应条件
Mg,Al,Hg,Fe,Ni,Pb or Sn in neat (no solvent)
react. of PF3Cl2 on heating with Mg, Al, Hg, Fe, Ni, Pb or Sn at 180°C;;
参考文献
Poulenc, C.
C. r. Acad. Sci. (Paris), 1891 , vol. 113, p. 75 - 78
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
byproducts: (NHMe3)Br; absence of air and moisture (vac. line); condensing NMe3 onto mixt. of NH(PF2)2 and SiBrH3, warming to room temp. for 15 s; fractional distn.;
参考文献
Ebsworth, E. A. V.; Rankin, David W. H.; Wright, John G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1065 - 1069
参考文献
Emeleus, H. J.; Hurst, G. L.
Journal of the American Chemical Society, 1964 , p. 396 - 399
